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Helium gas with a volume of 2.60 \(\mathrm{L}\) , under a pressure of 1.30 atm and at a temperanure of \(41.0^{\circ} \mathrm{C},\) is warmed until both pressure and volume are doubled. (a) What is the final temperature? (b) How many grams of helium are there? The molar mass of helium is 4.00 \(\mathrm{g} / \mathrm{mol.}\)

Short Answer

Expert verified
Final temperature is approximately 628.3 K. Mass of helium is approximately 0.524 g.

Step by step solution

01

Convert Initial Temperature to Kelvin

The initial temperature is given in Celsius, which needs to be converted to Kelvin. The conversion formula is: \( T(K) = T(°C) + 273.15 \). Thus, \( T(1) = 41.0 + 273.15 = 314.15 \ \mathrm{K}.\)
02

Apply the Combined Gas Law

The combined gas law is \( \frac{P_1V_1}{T_1} = \frac{P_2V_2}{T_2} \). With \( P_2 = 2 \cdot 1.30\, \mathrm{atm},\) and \( V_2 = 2 \cdot 2.60\, \mathrm{L} \), we need to find \( T_2 \). Rearrange the formula to solve for \( T_2 \): \( T_2 = \frac{P_2V_2T_1}{P_1V_1} \).
03

Substitute and Calculate Final Temperature

Substitute known values into the rearranged formula: \( T_2 = \frac{(2 \times 1.30) \times (2 \times 2.60) \times 314.15}{1.30 \times 2.60} \). Work through the calculation: \( T_2 = \frac{6.76 \times 314.15}{3.38} \approx 628.3\, \mathrm{K}.\)
04

Calculate Moles of Helium

Use the ideal gas law \( PV = nRT \) to find the number of moles. First rearrange to solve for \( n \): \( n = \frac{PV}{RT} \). Use \( P = 1.30 \ \mathrm{atm}, \ V = 2.60 \ \mathrm{L}, \) and \( R = 0.0821 \ \mathrm{L} \cdot \mathrm{atm}/\mathrm{mol} \cdot \mathrm{K},\) with initial temperature \( T_1 = 314.15\, \mathrm{K}.\)
05

Substitute and Calculate Moles

Substitute the values into the ideal gas law formula: \( n = \frac{1.30 \times 2.60}{0.0821 \times 314.15} \). Calculate \( n = \frac{3.38}{25.79} \approx 0.131 \ \mathrm{mol}.\)
06

Calculate Mass of Helium

Use the molar mass of helium to find the mass: \( \text{mass} = n \times \text{molar mass} \). Thus, \( \text{mass} = 0.131 \times 4.00 \approx 0.524 \ \mathrm{g}.\)

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Combined Gas Law
The Combined Gas Law is an essential concept in chemistry that combines three different gas laws: Boyle's Law, Charles's Law, and Gay-Lussac's Law. It allows us to understand how pressure, volume, and temperature interact with each other for a given amount of gas, provided no gas particles are added or removed.
Where the ideal gas law formula is represented as:
  • \( \frac{P_1V_1}{T_1} = \frac{P_2V_2}{T_2} \).
  • P represents pressure, V is volume, and T is temperature in Kelvin.
  • Subscripts 1 and 2 refer to initial and final states, respectively.
To properly utilize the Combined Gas Law, temperature must always be expressed in Kelvin. This preserves the absolute scale of temperature. In our exercise, Helium gas originally at 314.15K saw its pressure and volume both double, requiring us to solve for the final temperature \( T_2 \). The final temperature determined via substitution is approximately 628.3K, demonstrating how precise adjustments in conditions alter the thermodynamic state.
Helium Gas Calculations
Calculating the properties of helium, like any other gas, can be effectively done using the ideal gas equation: \( PV = nRT \), where \( n \) represents the number of moles, \( R \) is the universal gas constant, \( 0.0821 \ \mathrm{L \, atm/mol \, K} \), and \( P \), \( V \), and \( T \) denote pressure, volume, and temperature respectively.
The initial scenario outlines the use of conditions where Helium occupies 2.6 L, is under 1.30 atm of pressure at 314.15K. By substituting these into the ideal gas law, we solve for moles \( n \) as:
  • \( n = \frac{PV}{RT} = \frac{1.30 \times 2.60}{0.0821 \times 314.15} \approx 0.131 \ \mathrm{mol} \).
Through this computation, we understand that the moles of helium involved are 0.131, which is crucial for determining further properties like mass.
Molar Mass Calculations
Conducting molar mass calculations enables chemists to convert between moles of a substance and its mass, and this is vital for any quantitative analysis involving gases. The molar mass of helium is known to be 4.00 g/mol.
Once the amount in moles is known, the mass of helium can be calculated using the simple equation:
  • \( \text{mass} = n \times \text{molar mass} \).
For our example, using the determined amount of Helium, which is 0.131 mol, we calculate the mass by:
  • \( \text{mass} = 0.131 \times 4.00 \approx 0.524 \ \mathrm{g} \).
This calculation illustrates the conversion of a molecular quantity into a tangible mass, showcasing how closely the notion of moles interconnects with chemical mass.

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Most popular questions from this chapter

The gas inside a balloon will always have a pressure nearly equal to atnospheric pressure, since that is the pressure applied to the outside of the balloon. You fill a balloon with helium (a nearly ideal gas to a volume of 0.600 \(\mathrm{L}\) at a tenperature of \(19.0^{\circ} \mathrm{C} .\) What is the volume of the balloon if you cool it to the boiling point of liguid nitrogen \((77.3 \mathrm{K}) ?\)

Consider 5.00 mol of liquid water. (a) What volume is occupied by this amount of water? The molar mass of water is 18.0 \(\mathrm{g} / \mathrm{mol}\) (b) Imagine the molecules to be, on average, uniformly spaced, with each molecule at the center of a small cube. What is the length of an edge of each small cube if adjacent cubes touch but don't overlap? (c) How does this distance compare with the diameter of a molecule?

The vapor pressure is the pressure of the vapor phase of a substance when it is in equilibrium with the solid or liquid phase of the substance. The relative humidity is the partial pressure of water vapor in the air divided by the vapor pressure of water at that same terperature, expressed as a percentage. The air is saturated when the humidity is 100\(\%\) . (a) The vapor pressure of water at \(20.0^{\circ} \mathrm{C}\) is \(2.34 \times 10^{3} \mathrm{Pa}\) . If the air temperature is \(20.0^{\circ} \mathrm{C}\) and the relative humidity is 60\(\%\) what is the partial pressure of water vapor in the atmosphere (that is, the pressure due to water vapor alone)? (b) Under the conditions of part (a), what is the mass of water in 1.00 \(\mathrm{m}^{3}\) of air? (The molar mass of water is 18.0 \(\mathrm{g} / \mathrm{mol}\) . Assume that water vapor can be treated as an ideal gas.)

Modern vacuum pumps make it easy to attain pressures of the order of \(10^{-13}\) atm in the laboratory. (a) At a pressure of \(9.00 \times 10^{-14}\) am and an ordinary temperature of \(300.0 \mathrm{K},\) how many inolecules are present in a volume of 1.00 \(\mathrm{cm}^{3} ?\) (b) How many molecules would be present at the same temperature but at 1.00 atm instead?

Calculate the mean free path of air molecules at a pressure of \(3.50 \times 10^{-13}\) atm and a temperature of 300 \(\mathrm{K}\) . (This pressure is readily attainable in the laboratory; see Exercise 18.24 .) As in Example \(18.8,\) model the air molecules as spheres of radius \(2.0 \times 10^{-10} \mathrm{m}\).

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