/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Problem 11 The gas inside a balloon will al... [FREE SOLUTION] | 91Ó°ÊÓ

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The gas inside a balloon will always have a pressure nearly equal to atnospheric pressure, since that is the pressure applied to the outside of the balloon. You fill a balloon with helium (a nearly ideal gas to a volume of 0.600 \(\mathrm{L}\) at a tenperature of \(19.0^{\circ} \mathrm{C} .\) What is the volume of the balloon if you cool it to the boiling point of liguid nitrogen \((77.3 \mathrm{K}) ?\)

Short Answer

Expert verified
The volume of the balloon is approximately 0.1588 L.

Step by step solution

01

Understand the Problem

The problem involves a balloon with helium gas cooled to a specific temperature. We need to find out how the volume will change when the temperature is decreased from \(19.0^{\circ} \mathrm{C}\) to the boiling point of liquid nitrogen, \(77.3 \mathrm{K}\).
02

Identify Relevant Concepts

This problem involves the Ideal Gas Law and Charles's Law, which states that for a given amount of gas at constant pressure, the volume of the gas is directly proportional to its temperature in Kelvin.
03

Convert Celsius to Kelvin

Convert the initial temperature from Celsius to Kelvin. Kelvin is the standard unit used in gas law calculations.\[ T_1 = 19.0 + 273.15 = 292.15 \, \mathrm{K} \]
04

Apply Charles's Law

Charles's Law is given by \( \frac{V_1}{T_1} = \frac{V_2}{T_2} \), where \(V_1\) and \(T_1\) are the initial volume and temperature, and \(V_2\) and \(T_2\) are the final volume and temperature. Rearrange the formula to solve for the final volume, \(V_2\):\[ V_2 = V_1 \times \frac{T_2}{T_1} \]
05

Substitute Known Values

Substitute the known values into the equation:\[ V_2 = 0.600 \, \mathrm{L} \times \frac{77.3 \, \mathrm{K}}{292.15 \, \mathrm{K}} \]
06

Calculate the Final Volume

Perform the calculation:\[ V_2 = 0.600 \, \mathrm{L} \times 0.2646 \approx 0.1588 \, \mathrm{L} \]
07

Result

Therefore, the final volume of the balloon is approximately \(0.1588 \, \mathrm{L}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Ideal Gas Law
The Ideal Gas Law is a powerful equation used to relate the pressure, volume, temperature, and amount of a gas. Its formula is given by:\[ PV = nRT \]where,
  • P is the pressure of the gas.
  • V is the volume of the gas.
  • n is the amount of gas in moles.
  • R is the ideal gas constant.
  • T is the temperature of the gas in Kelvin.
The Ideal Gas Law helps predict how a gas behaves under various conditions. It is particularly relevant when assessing changes in volume and temperature without altering the quantity of the gas particles involved. In the context of our problem, this law supports the understanding that as temperature decreases, the volume tends to decrease as well, given a constant pressure.
temperature conversion
When performing gas law calculations, it's crucial to use the Kelvin scale for temperature. This is due to Kelvin being the absolute temperature scale, where zero reflects the absence of thermal energy. To convert from Celsius to Kelvin, add 273.15 to the Celsius temperature. This transformation is necessary to ensure that the gas laws operate correctly, given they require absolute temperatures for accurate predictions.

For example, in the provided exercise, the initial temperature is given as 19.0°C. To convert this to Kelvin, you add:\[ 19.0 + 273.15 = 292.15\, \mathrm{K} \]Converting temperatures to Kelvin eliminates risks of mathematical errors related to negative temperatures, ensuring a straightforward application of Charles's Law.
helium gas
Helium is a lightweight, inert gas that is frequently used in balloons due to its low density and non-reactive nature. It is considered nearly ideal because it adheres closely to the behavior predicted by the Ideal Gas Law. This means its molecules have minimal interactions with each other, and they occupy negligible space compared to the volume of the container they are in.

Given its simplicity and predictable behavior, helium serves as an excellent example when learning about gas laws. In experiments and calculations, helium's behavior will often align with theoretical predictions, allowing students to accurately apply equations such as Charles's Law to determine changes in volume with temperature.
liquid nitrogen boiling point
Liquid nitrogen boils at a strikingly low temperature of 77.3 Kelvin (-195.85°C). This cryogenic boiling point is instrumental in numerous scientific and commercial applications, especially those requiring severe temperature conditions, like cryopreservation and material testing.

When helium gas in a balloon is cooled to this temperature, it provides a practical example of Charles's Law. According to this law, a gas will decrease in volume as its temperature drops at constant pressure. Thus, understanding the boiling point of liquid nitrogen allows students to visualize and comprehend how drastic temperature changes can affect gas volume. In this way, liquid nitrogen serves as a critical reference point in learning temperature-related gas behaviors.

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Most popular questions from this chapter

(a) Oxygen \(\left(\mathrm{O}_{2}\right)\) has a molar mass of 32.0 \(\mathrm{g} / \mathrm{mol}\) . What is the average translational kinetic energy of an oxygen molecule at a temperature of 300 \(\mathrm{K} ?\) (b) What is the average value of the square at a of its speed? (c) What is the root-mean-square speed? (d) What is the momentum of an oxygen molecule traveling at this speed? (e) Suppose an oxygen molecule traveling at this speed bounces back and forth between opposite sides of a cubical vessel 0.10 \(\mathrm{m}\) on a side. What is the average force the molecule exerts on one of the walls of the container? (Assume that the molecule's velocity is perpendicular to the two sides that it strikes.) (f) What is the aver- age force per unit area? (g) How many oxygen molecules traveling at this speed are necessary to produce an average pressure of 1 \(\mathrm{atm} ?\) (h) Compute the number of oxygen molecules that are actually contained in a vessel of this size at 300 \(\mathrm{K}\) and atmospheric pressure. (i) Your answer for part (h) should be three times as large as the answer for part (g). Where does this discrepancy arise?

A metal tank with volume 3.10 L will burst if the absolute pressure of the gas it contains exceeds 100 atm. (a) If 11.0 mol of an ideal gas is put into the tank at a temperature of \(23.0^{\circ} \mathrm{C},\) to what temperature can the gas be warmed before the tank ruptures? You can ignore the thermal expansion of the tank. (b) Based on your answer to part (a), is it reasonable to ignore the thermal expansion of the tank? Explain.

We have two equal-size boxes, \(A\) and \(B\) . Each box contains gas that behaves as an ideal gas. We insert a thermometer into each box and find that the gas in box \(A\) is at a temperature of \(50^{\circ} \mathrm{C}\) while the gas in box \(B\) is at \(10^{\circ} \mathrm{C}\) . This is all we know about the gas in the boxes. Which of the following statements must be true? Which could be true? (a) The pressure in \(A\) is higher than in \(B\) . There are more molecules in \(A\) than in \(B .(\mathrm{c}) A\) and \(B\) cannot contain the same type of gas. (d) The molecules in \(A\) have more average kinetic energy per molecule than those in \(B\) . (e) The molecules in \(A\) are moving faster than those in \(B\) . Explain the reasoning behind your answers.

You blow up a spherical balloon to a diameter of 50.0 \(\mathrm{cm}\) until the absolute pressure inside is 1.25 atm and the temperature is \(22.0^{\circ} \mathrm{C}\) . Assume that all the gas in \(\mathrm{N}_{2}\) is of molar mass 28.0 \(\mathrm{g} / \mathrm{mol}\) . (a) Find the mass of a single \(\mathrm{N}_{2}\) molecule. (b) How much translational kinetic energy does an average \(\mathrm{N}_{2}\) molecule have? (c) How many \(\mathrm{N}_{2}\) molecules are in this balloon? (d) What is the total translational kinetic energy of all the inolecules in the balloon?

An empty cylindrical canister 1.50 \(\mathrm{m}\) long and 90.0 \(\mathrm{cm}\) in diameter is to be filled with pure oxygen at \(22.0^{\circ} \mathrm{C}\) to sture in a space station. To hold as thuch gas as possible, the absolute pressure of the oxygen will be 21.0 atm. The molar mass of oxygen is 32.0 \(\mathrm{g} / \mathrm{mol}\) . (a) How many tholes of oxygen does this canister hold? (b) For someone lifting this canister, by how many kilo-grams does this gas increase the mass to be lifted?

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