Chapter 19: Problem 14
Explain why the average velocity of air molecules in a closed auditorium is zero but their root-mean-square speed or average speed is not zero.
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Chapter 19: Problem 14
Explain why the average velocity of air molecules in a closed auditorium is zero but their root-mean-square speed or average speed is not zero.
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1 .00 mol of molecular nitrogen gas expands in volume very quickly, so no heat is exchanged with the environment during the process. If the volume increases from \(1.00 \mathrm{~L}\) to \(1.50 \mathrm{~L},\) determine the work done on the environment if the gas's temperature dropped from \(22.0^{\circ} \mathrm{C}\) to \(18.0^{\circ} \mathrm{C}\). Assume ideal gas behavior.
A tank of compressed helium for inflating balloons is advertised as containing helium at a pressure of 2400 psi, which, when allowed to expand at atmospheric pressure, will occupy a volume of \(244 \mathrm{ft}^{3}\). Assuming no temperature change takes place during the expansion, what is the volume of the tank in cubic feet?
Treating air as an ideal gas of diatomic molecules, calculate how much heat is required to raise the temperature of the air in an \(8.00 \mathrm{~m}\) by \(10.0 \mathrm{~m}\) by \(3.00 \mathrm{~m}\) room from \(20.0^{\circ} \mathrm{C}\) to \(22.0^{\circ} \mathrm{C}\) at \(101 \mathrm{kPa}\). Neglect the change in the number of moles of air in the room.
Interstellar space far from any stars is usually filled with atomic hydrogen (H) at a density of 1 atom/cm \(^{3}\) and a very low temperature of \(2.73 \mathrm{~K}\). a) Determine the pressure in interstellar space. b) What is the root-mean-square speed of the atoms? c) What would be the edge length of a cube that would contain atoms with a total of \(1.00 \mathrm{~J}\) of energy?
The Maxwell speed distribution assumes that the gas is in equilibrium. Thus, if a gas, all of whose molecules were moving at the same speed, were given enough time, they would eventually come to satisfy the speed distribution. But the kinetic theory derivations in the text assumed that when a gas molecule hits the wall of a container, it bounces back with the same energy it had before the collision and that gas molecules exert no forces on each other. If gas molecules exchange energy neither with the walls of their container nor with each other, how can they ever come to equilibrium? Is it not true that if they all had the same speed initially, some would have to slow down and others speed up, according to the Maxwell speed distribution?
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