Chapter 18: Problem 7
Water has a mass per mole of \(18.0 \mathrm{g} / \mathrm{mol},\) and euch water molecule (H, O ) has 10 clectrons. (a) How many clectrons are there in onc liter \(\left(1.00 \times 10^{-3} \mathrm{m}^{3}\right)\) of water? (b) What is the net charge of all these electrons?
Short Answer
Expert verified
(a) \(3.34 \times 10^{26}\) electrons, (b) \(-5.34 \times 10^{7} \text{ C}\).
Step by step solution
01
Find the number of moles in 1 liter of water
The density of water is approximately \(1 \text{ g/mL}\), which means \(1\text{ L}\) of water has a mass of \(1000 \text{ g}\). We use the formula for moles \( n = \frac{\text{mass}}{\text{molar mass}} \). Here the molar mass is \(18.0 \text{g/mol}\). Substitute the mass of water:\[ n = \frac{1000 \text{ g}}{18.0 \text{ g/mol}} \approx 55.56 \text{ mol} \]
02
Calculate the number of water molecules
Avogadro's number, \( 6.022 \times 10^{23} \text{ molecules/mol} \), gives the number of molecules per mole. Multiply the moles of water by Avogadro's number:\[ \text{No. of molecules} = 55.56 \text{ mol} \times 6.022 \times 10^{23} \text{ molecules/mol} \approx 3.34 \times 10^{25} \text{ molecules} \]
03
Determine the total number of electrons
Each water molecule has 10 electrons. Therefore, multiply the number of molecules by the number of electrons per molecule:\[ \text{Total electrons} = 3.34 \times 10^{25} \text{ molecules} \times 10 \text{ electrons/molecule} \approx 3.34 \times 10^{26} \text{ electrons} \]
04
Calculate the net charge of the electrons
The charge of a single electron is \(-1.60 \times 10^{-19} \text{ C/electron}\). Multiply the total number of electrons by this charge:\[ \text{Net charge} = 3.34 \times 10^{26} \text{ electrons} \times (-1.60 \times 10^{-19} \text{ C/electron}) \approx -5.34 \times 10^{7} \text{ C} \]
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Density of Water
Water is a unique substance with a consistent density, which is approximately 1 gram per milliliter (g/mL). This means that in a standard atmospheric condition, each liter of water weighs approximately 1000 grams. This property is pivotal for various calculations in chemistry, particularly when converting between volume and mass.
- This density value allows for straightforward conversion: 1 liter of water equals 1000 grams.
- It is a fundamental constant used in scientific calculations involving water.
- Understanding this concept is crucial for determining how much matter is present in a given volume of water.
Avogadro's Number
Avogadro's Number, represented as \(6.022 \times 10^{23}\), is an essential constant in chemistry. It denotes the number of particles, typically atoms or molecules, in one mole of a substance.
- This number serves as a bridge between the macroscopic scale, which we can measure, and the microscopic scale of atoms and molecules.
- In practical terms, it allows us to quantify atoms or molecules by measuring mass, turning grams into moles.
- In exercises like the one provided, Avogadro's number is used to convert the number of moles of water into the actual number of molecules.
Electron Charge
Electrons are subatomic particles with a negative electric charge, typically measured in Coulombs (C). Each electron carries a charge of \(-1.60 \times 10^{-19}\) C. This charge is small but fundamental to understanding atomic interactions and chemical reactions.
- In a single water molecule, there are ten electrons, each contributing to the molecule's overall electronic characteristics.
- The net charge of a group of electrons is calculated by multiplying the number of electrons by the charge per electron.
- Understanding electron charge is crucial when exploring electrical properties of substances and the flow of electrons in electric currents.
Molar Mass Calculation
Molar mass is a substance's mass per mole, commonly expressed in grams per mole (g/mol). For water, the molar mass is calculated as 18.0 g/mol.
- The molar mass is derived from the individual atomic masses of hydrogen and oxygen; here, hydrogen contributes about 1.0 g/mol, and oxygen contributes about 16.0 g/mol.
- To find the number of moles in a substance, you divide the mass of the substance by its molar mass using the formula: \( n = \frac{\text{mass}}{\text{molar mass}} \).
- This calculation is crucial for converting mass into a usable form for further calculations like the number of molecules or atoms.