Chapter 5: Problem 37
Consider a two-level system with \(E_{1}
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Chapter 5: Problem 37
Consider a two-level system with \(E_{1}
These are the key concepts you need to understand to accurately answer the question.
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This chapter derived two of the three relativistic corrections to the one- electron atom, namely \(\Delta_{K}^{(1)}\) from "relativistic kinetic energy," and \(\Delta_{L S}^{(1)}\) from the spin-orbit interaction. A third term comes from the spread of the electron wave function in the region of changing electric field. The perturbation for this "Darwin term" is $$ V_{D}=-\frac{1}{8 m^{2} c^{2}} \sum_{i=1}^{3}\left[p_{i},\left[p_{i}, e \phi(r)\right]\right] $$ where \(\phi(r)\) is the Coulomb potential. Find \(\Delta_{D}^{(1)}\) and show that $$ \Delta_{n j}^{(1)} \equiv \Delta_{K}^{(1)}+\Delta_{L S}^{(1)}+\Delta_{D}^{(1)}=\frac{m c^{2}(Z \alpha)^{4}}{2 n^{3}}\left[\frac{3}{4 n}-\frac{1}{j+1 / 2}\right] . $$ In Section \(8.4\) we will compare this expression to the result of solving the Dirac equation in the presence of the Coulomb potential.
A diatomic molecule can be modeled as a rigid rotor with moment of inertia \(I\) and an electric dipole moment \(d\) along the axis of the rotor. The rotor is constrained to rotate in a plane, and a weak uniform electric field \(\mathscr{E}\) lies in the plane. Write the classical Hamiltonian for the rotor, and find the unperturbed energy levels by quantizing the angular- momentum operator. Then treat the electric field as a perturbation, and find the first nonvanishing corrections to the energy levels.
Suppose the electron had a very small intrinsic electric dipole moment analogous to the spin magnetic moment (that is, \(\mu_{e l}\) proportional to \(\sigma\) ). Treating the hypothetical \(-\mu_{e l} \cdot \mathbf{E}\) interaction as a small perturbation, discuss qualitatively how the energy levels of the Na atom \((Z=11)\) would be altered in the absence of any external electromagnetic field. Are the level shifts first order or second order? State explicitly which states get mixed with each other. Obtain an expression for the energy shift of the lowest level that is affected by the perturbation. Assume throughout that only the valence electron is subjected to the hypothetical interaction.
Consider an isotropic harmonic oscillator in two dimensions. The Hamiltonian is $$ H_{0}=\frac{p_{x}^{2}}{2 m}+\frac{p_{y}^{2}}{2 m}+\frac{m \omega^{2}}{2}\left(x^{2}+y^{2}\right) $$ a. What are the energies of the three lowest-lying states? Is there any degeneracy? b. We now apply a perturbation $$ V=\delta m \omega^{2} x y $$ where \(\delta\) is a dimensionless real number much smaller than unity. Find the zerothorder energy eigenket and the corresponding energy to first order [that is, the unperturbed energy obtained in (a) plus the first-order energy shift] for each of the three lowest-lying states. c. Solve the \(H_{0}+V\) problem exactly. Compare with the perturbation results obtained in (b).
A one-electron atom whose ground state is nondegenerate is placed in a uniform electric field in the \(z\)-direction. Obtain an approximate expression for the induced electric dipole moment of the ground state by considering the expectation value of ez with respect to the perturbed state vector computed to first order. Show that the same expression can also be obtained from the energy shift \(\Delta=-\alpha|\mathbf{E}|^{2} / 2\) of the ground state computed to second order. (Note: \(\alpha\) stands for the polarizability.) Ignore spin.
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