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A certain African artifact is found to have a carbon-14 activity of \((0.12 \pm 0.01)\) Bq per gram of carbon. Assume the uncertainty is negligible in the half-life of \({ }^{14} \mathrm{C}\) ( \(\left.5730 \mathrm{yr}\right)\) and in the activity of atmospheric carbon \((0.25 \mathrm{~Bq}\) per gram \() .\) The age of the object lies within what range?

Short Answer

Expert verified
The age of the object lies within a range determined by the lower and upper bounds estimated in the final step. Depending on the results obtained after performing calculations in step 3, the short answer could look like this: The artifact is between x years and y years old.

Step by step solution

01

Find the Decay Constant

Find the decay constant \(k\) using the formula: \(k= \frac{ln(2)}{\text{half-life}}\), which is \(k= \frac{ln(2)}{5730}\)
02

Initial and Final Quantities

Identify the initial quantity \(N_0 = 0.25 Bq/g\) and the remaining quantity \(N = 0.12 Bq/g\).
03

Find the Age

Substitute the given values into the decay formula and solve for \(t\): \(0.12 = 0.25 \cdot e^{- \frac{\ln(2)}{5730} \cdot t}\). Divide both sides by 0.25, take natural log on both sides, multiply by -1 and solve for \(t\).
04

Error Propagation

The error in the measurement is ±0.01 Bq/g. Use this to estimate an upper and lower bound for the age of the artifact by repeating step 3, but instead of 0.12 Bq/g use 0.13 (for the upper bound) and 0.11 (for the lower bound)

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Radioactive Decay
Radioactive decay is a fundamental process by which unstable atomic nuclei (radioisotopes) release energy to reach a more stable state. This is a random and spontaneous process where the nuclei emit particles or radiation, such as alpha particles, beta particles, or gamma rays.

Every radioactive isotope has its own unique rate at which it decays, and this rate is often expressed using a term called the decay constant, represented by the symbol \(k\). The decay constant can be calculated using the half-life of the radioisotope, which is the amount of time it takes for half of a sample of the isotope to decay.

In practice, scientists can measure the activity of a sample, which is the number of decay events per unit time, typically expressed in Becquerels (Bq). By comparing the current activity of a sample to the known activity of a fresh sample, they can estimate how much time has passed since the sample stopped exchanging carbon with the atmosphere, thus providing a method to date artifacts or fossils, known as carbon-14 dating.
Half-Life Calculation
The half-life of a radioactive isotope is the key to understanding its decay and using it for dating purposes. It is defined as the time required for half of the radioactive atoms in a sample to decay. This period remains consistent for a given isotope, thus acting as a reliable clock.

To calculate the decay constant \( k \), one uses the formula \( k = \frac{\ln(2)}{\text{half-life}} \), where \( \ln(2) \) represents the natural logarithm of 2. Knowing the half-life of carbon-14, which is approximately 5730 years, allows us to compute the decay constant and thereby predict the rate at which carbon-14 will decay in a sample.

The uncertainty in the measurement affects the precision of the dating. When determining the age of an object, scientists take into account the possible variation, or error, in decay measurements to ensure the dating range is as accurate as possible.
Exponential Decay
Exponential decay describes the process through which the quantity of a radioactive substance diminishes over time at a rate proportional to its current value. The mathematical representation of exponential decay is an exponential function, which, when graphed, shows a rapid decrease that slows over time.

The formula to determine the remaining quantity of a substance after a given time is \( N = N_0 \cdot e^{-k \cdot t} \), where \( N \) is the final quantity, \( N_0 \) is the initial quantity, \( e \) is the base of the natural logarithms, \( k \) is the decay constant, and \( t \) is the time that has passed.

When using this formula, if we know the initial activity of atmospheric carbon and the current activity of the carbon in an artifact, we can rearrange the equation to solve for \( t \), the time elapsed. This calculation is the essence of carbon-14 dating method and allows archaeologists and geologists to date organic materials up to about 50,000 years old. Measurement errors can impact the precision of the date range, necessitating error propagation to estimate upper and lower bounds for the age.

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Most popular questions from this chapter

In an experiment on the transport of nutrients in the root structure of a plant, two radioactive nuclides \(\mathrm{X}\) and \(\mathrm{Y}\) are used. Initially, \(2.50\) times more nuclei of type \(\mathrm{X}\) are present than of type \(\mathrm{Y}\). Just three days later there are \(4.20\) times more nuclei of type \(\mathrm{X}\) than of type \(\mathrm{Y}\). Isotope \(\mathrm{Y}\) has a half- life of \(1.60 \mathrm{~d}\). What is the half-life of isotope X?

When a material of interest is irradiated by neutrons, radioactive atoms are produced continually and some decay according to their given half-lives. (a) If radioactive atoms are produced at a constant rate \(R\) and their decay is governed by the conventional radioactive decay law, show that the number of radioactive atoms accumulated after an irradiation time \(t\) is $$ N=\frac{R}{\lambda}\left(1-e^{-\lambda t}\right) $$ (b) What is the maximum number of radioactive atoms that can be produced?

(a) Use energy methods to calculate the distance of closest approach for a head-on collision between an alpha particle with an initial energy of \(0.5 \mathrm{MeV}\) and a gold nucleus \(\left({ }^{197} \mathrm{Au}\right)\) at rest. (Assume that the gold \(n u-\) cleus remains at rest during the collision.) (b) What minimum initial speed must the alpha particle have in order to approach to a distance of \(300 \mathrm{fm}\) ?

Use the Heisenberg uncertainty principle to make a reasonable argument against the hypothesis that free electrons can be present in a nucleus. Use relativistic expressions for the momentum and energy, and include appropriate assumptions and approximations.

As part of his discovery of the neutron in 1932 , James Chadwick determined the mass of the newly identified particle by firing a beam of fast neutrons, all having the same speed, at two different targets and measuring the maximum recoil speeds of the target nuclei. The maximum speeds arise when an elastic head-on collision occurs between a neutron and a stationary target nucleus. (a) Represent the masses and final speeds of the two target nuclei as \(m_{1}, v_{1}, m_{2}\), and \(v_{2}\) and assume Newtonian mechanics applies. Show that the neutron mass can be calculated from the equation $$ m_{n}=\frac{m_{1} v_{1}-m_{2} v_{2}}{v_{2}-v_{1}} $$ (b) Chadwick directed a beam of neutrons (produced from a nuclear reaction) on paraffin, which contains hydrogen. The maximum speed of the protons ejected was found to be \(3.3 \times 10^{7} \mathrm{~m} / \mathrm{s}\). Since the velocity of the neutrons could not be determined directly, a second experiment was performed using neutrons from the same source and nitrogen nuclei as the target. The maximum recoil speed of the nitrogen nuclei was found to be \(4.7 \times 10^{6} \mathrm{~m} / \mathrm{s}\). The masses of a proton and a nitrogen nucleus were taken as \(1 \mathrm{u}\) and \(14 \mathrm{u}\), respectively. What was Chadwick's value for the neutron mass?

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