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According to the energy-time uncertainty principle, the lifetimelof a state and the uncertaintyEin its energy are invertible proportional. Hydrogen's red spectral line is the result of an electron making a transition "downward" frum a quantum state whose lifetime is about10-8s.

(a) What inherent uncertainty in the energy of the emitted person does this imply? (Note: Unfortunately. we might use the symbol for the energy difference-i.e., the energy of the photon-but here it means the uncertainly in that energy difference.)

(b) To what range in wavelength s does this correspond? (As noted in Exercise 2.57. the uncertainty principle is one contributor to the broadening of spectral lines.)

(c) Obtain a general formula relating tot.

Short Answer

Expert verified

(a)E5.2710-27J(b)1.1410-14m(c)t24蟺肠

Step by step solution

01

The Heisenberg uncertainty principle

The Heisenberg uncertainty principle relating an uncertainty in energy Ewith an uncertainty in time tare related as

Eth2

Here, his reduced Planck's constant.

Energy E of a photon with wavelength is given by

E=hc

Here, h is Planck's constant, and c is speed of light in vacuum.

02

 Determine the energy of the emitted person

(a)

As given Wavelength=656nm=(656nm)10-9mnm=65610-9m

The uncertainty in time t=10-ss

All values, 10-8sfor the uncertainty in time t, and 1.054610-34J.sforh is taken in the equation uncertainty in energy E

Et'EEh2tE(1.054610-34J.s)2(10-8s)E5.27310-27J

Therefore, uncertainty in energy for that quantum level E5.2710-27J.

03

 Step 2: determine the derivation on both sides of  E=hcλ

(b)

The photon鈥檚 energy comprises of

E=hc

Take the derivation on both sides

dE=hcd-2hcdE=d

As we are only interested in the magnitude of the change in wavelength, the absolute value

d=2hcdE

Take 6.6310-34J.sforh,3108m/sforcand5.2710-27JfordEin the above equation to solve for

d=2hcdEd=(6.5610-7m)2(6.6310-34J.s)(3108m/s)5.2710-27Jd=1.1410-14m

Hence, the range of wavelengths for the 656 nm spectral line is 1.1410-14m.

04

Find the relationship between the ∆λ and ∆t 

(c)

The absolute value of the change in wavelength

d=2hcdE

For finite change, =2hcE

Take the value of hc2dforE,andh2forhin the equation Eth2

hc2th22ct214t24蟺肠

Hence, the relationship between the and tis t24蟺肠.

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