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Suppose that you warm up 500gof water (half a litre, or about a pint) on a stove while doing5脳10闯of work on the water with an electric beater. The temperature of the water is observed to rise from20oCto80oC. What was the change in the thermal energy of the water? Taking the water as the system, how much transfer of energyQdue to a temperature difference was there across the system boundary? What was the energy change of the surroundings?

Short Answer

Expert verified

For the amount of water heated the following observations are made:

Change in thermal energy of the water -螖贰thermal=1.26105J

Transfer of energy due to a temperature difference isQ=7.6104J

Energy change in the surroundings is螖贰surroundings=1.26105J

Step by step solution

01

Define the energy principle

The free energy principle defines how non-equilibrium steady-states are maintained in living and non-living systems by restricting their states to a minimal number. It establishes that systems minimise a free energy function of their internal states, implying hidden states in the environment.

02

Calculation of change in energy of water

Use the definition of thermal energy in order to obtain the change of energy in the water Ethermal.

螖贰thermal=(尘颁螖罢)H2O=(500g)(4.2JgoC)(80oC-20oC)=1.26脳105J

Therefore, the change in energy of water is obtained as Ethermal=1.26脳105J.

03

Equation for heat

According to the energy principle, this change of energy in the water is equal to the input of heat and work. Write this into an equation, in which then proceed to solve for the heat Q.

螖贰thermal=Q+W

Solve forQ and substitute the values,

Q=螖贰thermal-W=1.26脳105闯-5脳104J=7.6脳104J

Therefore, the equation of heat is obtained asQ=7.6脳104J .

04

Energy change in surroundings 

The energy gained by the mass of water is equal to the energy loss of the surroundings by considering the surroundings as everything but the mass of water.

Hence, the electric beater is also part of the surroundings.

Write the relation between energy of surrounding and thermal energy.

螖贰surroundings=螖贰thermal=1.26脳105J

Therefore, energy change in the surroundings is obtained as1.26脳105J .

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