Chapter 15: Problem 5
In your own words, briefly describe the phenomenon of viscoelasticity.
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Chapter 15: Problem 5
In your own words, briefly describe the phenomenon of viscoelasticity.
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Which of the following would you expect to be (-) elastomers and which thermosetting polymers at room temperature? Justify each choice. (a) Linear and highly crystalline polyethylene (b) Phenol-formaldehyde (c) Heavily crosslinked polyisoprene having a glass transition temperature of \(50^{\circ} \mathrm{C}\left(122^{\circ} \mathrm{F}\right)\) (d) Lightly crosslinked polyisoprene having a glass transition temperature of \(-60^{\circ} \mathrm{C}\left(-76^{\circ} \mathrm{F}\right)\) (e) Linear and partially amorphous poly(vinyl chloride)
What is the distinction between dye and pigment colorants?
For each of the following pairs of polymers do the following: (1) State whether it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (a) Branched polyethylene having a numberaverage molecular weight of \(850,000 \mathrm{~g} / \mathrm{mol}\); linear polyethylene having a number-average molecular weight of \(850,000 \mathrm{~g} / \mathrm{mol}\) (b) Polytetrafluoroethylene having a density of \(2.14 \mathrm{~g} / \mathrm{cm}^{3}\) and a weight-average molecular weight of \(600,000 \mathrm{~g} / \mathrm{mol}\); PTFE having a density of \(2.20\) \(\mathrm{g} / \mathrm{cm}^{3}\) and a weight-average molecular weight of \(600,000 \mathrm{~g} / \mathrm{mol}\) (c) Linear and syndiotactic poly(vinyl chloride). having a number-average molecular weight of \(500,000 \mathrm{~g} / \mathrm{mol}\); linear polyethylene having a numberaverage molecular weight of \(225,000 \mathrm{~g} / \mathrm{mol}\) (d) Linear and syndiotactic polypropylene having a weight-average molecular weight of 500,000 \(\mathrm{g} / \mathrm{mol}\); linear and atactic polypropylene having a weight-average molecular weight of \(750,000 \mathrm{~g} / \mathrm{mol}\)
On the basis of the curves in Figure \(15.5\), sketch schematic strain-time plots for the following polystyrene materials at the specified temperatures: (a) Crystalline at \(70^{\circ} \mathrm{C}\) (b) Amorphous at \(180^{\circ} \mathrm{C}\) (c) Crosslinked at \(180^{\circ} \mathrm{C}\) (d) Amorphous at \(100^{\circ} \mathrm{C}\).
For each of the following pairs of polymers, do ( the following: (1) State whether it is possible to decide whether one polymer has a higher tensile strength than the other; (2) if this is possible, note which has the higher tensile strength and cite the reason(s) for your choice; and (3) if it is not possible to decide, state why. (a) Linear and isotactic poly(vinyl chloride) with a weight-average molecular weight of \(100,000 \mathrm{~g} /\) mol; branched and atactic poly(vinyl chloride) having a weight-average molecular weight of \(75,000 \mathrm{~g} / \mathrm{mol}\) (b) Graft acrylonitrile-butadiene copolymer with \(10 \%\) of possible sites crosslinked; alternating acrylonitrile-butadiene copolymer with \(5 \%\) of possible sites crosslinked (c) Network polyester; lightly branched polytetrafluoroethylene
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