Chapter 15: Problem 42
What is the distinction between dye and pigment colorants?
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Chapter 15: Problem 42
What is the distinction between dye and pigment colorants?
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In your own words, describe the mechanisms by which semicrystalline polymers (a) elastically deform (b) plastically deform (c) by which elastomers elastically deform
The tensile strength and number-average mo( lecular weight for two polyethylene materials are as follows: $$ \begin{array}{cc} \hline \begin{array}{c} \text { Tensile } \\ \text { Strength (MPa) } \end{array} & \begin{array}{c} \text { Number-Average } \\ \text { Molecular Weight (g/mol) } \end{array} \\ \hline 90 & 20,000 \\ \hline 180 & 40,000 \\ \hline \end{array} $$ Estimate the number-average molecular weight that is required to give a tensile strength of \(140 \mathrm{MPa}\).
On the basis of the curves in Figure \(15.5\), sketch schematic strain-time plots for the following polystyrene materials at the specified temperatures: (a) Crystalline at \(70^{\circ} \mathrm{C}\) (b) Amorphous at \(180^{\circ} \mathrm{C}\) (c) Crosslinked at \(180^{\circ} \mathrm{C}\) (d) Amorphous at \(100^{\circ} \mathrm{C}\).
Normal butane and isobutane have boiling temperatures of \(-0.5^{\circ} \mathrm{C}\) and \(-12.3^{\circ} \mathrm{C}\) (31.1 \(\mathrm{F}\) and \(9.9^{\circ} \mathrm{F}\) ), respectively. Briefly explain this behavior. on the basis of their molecular structures, as presented in Section \(14.2\).
For each of the following pairs of polymers, plot and label schematic specific volume-versustemperature curves on the same graph [i.e., make separate plots for parts (a) to \((\mathrm{c})]\) (a) Linear polyethylene with a weight-average molecular weight of \(75,000 \mathrm{~g} / \mathrm{mol}\); branched polyethylene with a weight-average molecular weight of \(50,000 \mathrm{~g} / \mathrm{mol}\) (b) Spherulitic poly(vinyl chloride) of \(50 \%\) crystallinity and having a degree of polymerization of 5000 ; spherulitic polypropylene of \(50 \%\) crystallinity and degree of polymerization of 10,000 (c) Totally amorphous polystyrene having a degree of polymerization of 7000 ; totally amorphous polypropylene having a degree of polymerization of 7000
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