Chapter 15: Problem 37
List two important characteristics for polymers that are to be used in fiber applications.
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Chapter 15: Problem 37
List two important characteristics for polymers that are to be used in fiber applications.
These are the key concepts you need to understand to accurately answer the question.
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Briefly explain how each of the following influences the tensile modulus of a semicrystalline polymer and why: (a) molecular weight (b) degree of crystallinity (c) deformation by drawing (d) annealing of an undeformed material (e) annealing of a drawn material
Why must fiber materials that are melt-spun and then drawn be thermoplastic? Cite two reasons.
For each of the following pairs of polymers, plot and label schematic specific volume-versustemperature curves on the same graph [i.e., make separate plots for parts (a) to \((\mathrm{c})]\) (a) Linear polyethylene with a weight-average molecular weight of \(75,000 \mathrm{~g} / \mathrm{mol}\); branched polyethylene with a weight-average molecular weight of \(50,000 \mathrm{~g} / \mathrm{mol}\) (b) Spherulitic poly(vinyl chloride) of \(50 \%\) crystallinity and having a degree of polymerization of 5000 ; spherulitic polypropylene of \(50 \%\) crystallinity and degree of polymerization of 10,000 (c) Totally amorphous polystyrene having a degree of polymerization of 7000 ; totally amorphous polypropylene having a degree of polymerization of 7000
For each of the following pairs of polymers, plot and label schematic stress- strain curves on the same graph [i.e., make separate plots for parts (a) to \((\mathrm{c})]\) (a) Polyisoprene having a number-average molecular weight of \(100,000 \mathrm{~g} / \mathrm{mol}\) and \(10 \%\) of available sites crosslinked; polyisoprene having a numberaverage molecular weight of \(100,000 \mathrm{~g} / \mathrm{mol}\) and \(20 \%\) of available sites crosslinked (b) Syndiotactic polypropylene having a weightaverage molecular weight of \(100,000 \mathrm{~g} / \mathrm{mol}\); atactic polypropylene having a weight- average molecular weight of \(75,000 \mathrm{~g} / \mathrm{mol}\) (c) Branched polyethylene having a numberaverage molecular weight of \(90,000 \mathrm{~g} / \mathrm{mol}\); heavily crosslinked polyethylene having a number- average molecular weight of \(90,000 \mathrm{~g} / \mathrm{mol}\)
What is the distinction between dye and pigment colorants?
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