Chapter 15: Problem 38
Cite five important characteristics for polymers that are to be used in thin- film applications.
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Chapter 15: Problem 38
Cite five important characteristics for polymers that are to be used in thin- film applications.
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Normal butane and isobutane have boiling temperatures of \(-0.5\) and \(-12.3^{\circ} \mathrm{C}\) (31.1 and \(\left.9.9^{\circ} \mathrm{F}\right)\), respectively. Briefly explain this behavior on the basis of their molecular structures, as presented in Section 14.2.
In your own words, briefly describe the phenomenon of viscoelasticity.
Compute the weight percent sulfur that must be added to completely crosslink an alternating chloroprene-acrylonitrile copolymer, assuming that five sulfur atoms participate in each crosslink.
Make two schematic plots of the logarithm of relaxation modulus versus temperature for an amorphous polymer (curve \(C\) in Figure 15.8). (a) On one of these plots demonstrate how the behavior changes with increasing molecular weight. (b) On the other plot, indicate the change in behavior with increasing crosslinking.
(a) Compare the fatigue limits for polystyrene (Figure 15.11) and the cast iron for which fatigue data are given in Problem 8.20. (b) Compare the fatigue strengths at \(10^{6} \mathrm{cy}\) cles for poly(ethylene terephthalate) (PET, Figure 15.11) and red brass (Figure 8.34).
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