Chapter 15: Problem 38
Cite five important characteristics for polymers that are to be used in thin- film applications.
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Chapter 15: Problem 38
Cite five important characteristics for polymers that are to be used in thin- film applications.
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The vulcanization of polyisoprene is accomplished with sulfur atoms according to Equation 15.4. If \(57 \mathrm{wt} \%\) sulfur is combined with polyisoprene, how many crosslinks will be associated with each isoprene repeat unit if it is assumed that, on the average, six sulfur atoms participate in each crosslink?
(a) Compare the fatigue limits for polystyrene (Figure 15.11) and the cast iron for which fatigue data are given in Problem 8.20. (b) Compare the fatigue strengths at \(10^{6} \mathrm{cy}\) cles for poly(ethylene terephthalate) (PET, Figure 15.11) and red brass (Figure 8.34).
The tensile strength and number-average molecular weight for two polyethylene materials are as follows: \begin{tabular}{cc} \hline Tensile Strength (MPa) & Number-Average Molecular Weight \((\mathrm{g} / \mathbf{m o l})\) \\ \hline 85 & 12,700 \\ 150 & 28,500 \\ \hline \end{tabular} Estimate the number-average molecular weight that is required to give a tensile strength of \(195 \mathrm{MPa}\).
In Figure 15.28, the logarithm of \(E_{r}(t)\) versus the logarithm of time is plotted for polyisobutylene at a variety of temperatures. Make a plot of \(E_{r}(10)\) versus temperature and then estimate its \(T_{g}\).
Which of the following would you expect to be elastomers and which thermosetting polymers at room temperature? Justify each choice. (a) Epoxy having a network structure (b) Lightly crosslinked poly(styrenebutadiene) random copolymer that has a glass transition temperature of \(-50^{\circ} \mathrm{C}\) (c) Lightly branched and semicrystalline polytetrafluoroethylene that has a glass transition temperature of \(-100^{\circ} \mathrm{C}\) (d) Heavily crosslinked poly(ethylenepropylene) random copolymer that has a glass transition temperature of \(0^{\circ} \mathrm{C}\) (e) Thermoplastic elastomer that has a glass transition temperature of \(75^{\circ} \mathrm{C}\)
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