Chapter 13: Problem 15
(a) Explain why residual thermal stresses are introduced into a glass piece when it is cooled. (b) Are thermal stresses introduced upon heating? Why or why not?
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Chapter 13: Problem 15
(a) Explain why residual thermal stresses are introduced into a glass piece when it is cooled. (b) Are thermal stresses introduced upon heating? Why or why not?
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What is the distinction between glass transition temperature and melting temperature?
For many viscous materials, the viscosity \(\eta\) may be defined in terms of the expression $$ \eta=\frac{\sigma}{d \epsilon / d t} $$ where \(\sigma\) and \(d \epsilon / d t\) are, respectively, the tensile stress and the strain rate. A cylindrical specimen of a soda-lime glass of diameter 5 \(\mathrm{mm}(0.2\) in.) and length \(100 \mathrm{~mm}\) (4 in.) is subjected to a tensile force of \(1 \mathrm{~N}\left(0.224 \mathrm{lb}_{\mathrm{f}}\right)\) along its axis. If its deformation is to be less than \(1 \mathrm{~mm}(0.04\) in.) over a week's time, using Figure 13.7, determine the maximum temperature to which the specimen may be heated.
Cite one reason why drying shrinkage is greater for slip cast or hydroplastic products that have smaller clay particles.
The viscosity \(\eta\) of a glass varies with temperature according to the relationship $$ \eta=A \exp \left(\frac{Q_{\mathrm{vis}}}{R T}\right) $$ where \(Q_{\text {vis }}\) is the energy of activation for viscous flow, \(A\) is a temperature-independent constant, and \(R\) and \(T\) are, respectively, the gas constant and the absolute temperature. A plot of \(\ln \eta\) versus \(1 / T\) should be nearly linear, and with a slope of \(Q_{\text {vis }} / R\). Using the data in Figure 13.7, (a) make such a plot for the borosilicate glass, and (b) determine the activation energy between temperatures of 500 and \(900^{\circ} \mathrm{C}\).
From a molecular perspective, briefly explain the mechanism by which clay minerals become hydroplastic when water is added.
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