Chapter 13: Problem 10
What is the distinction between glass transition temperature and melting temperature?
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Chapter 13: Problem 10
What is the distinction between glass transition temperature and melting temperature?
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Glass pieces may also be strengthened by chemical tempering. With this procedure, the glass surface is put in a state of compression by exchanging some of the cations near the surface with other cations having a larger diameter. Suggest one type of cation that, by replacing \(\mathrm{Na}^{+}\), will induce chemical tempering in a soda-lime glass.
(a) What are the three main components of a whiteware ceramic such as porcelain? (b) What role does each component play in the forming and firing procedures?
The viscosity \(\eta\) of a glass varies with temperature according to the relationship $$ \eta=A \exp \left(\frac{Q_{\mathrm{vis}}}{R T}\right) $$ where \(Q_{\text {vis }}\) is the energy of activation for viscous flow, \(A\) is a temperature-independent constant, and \(R\) and \(T\) are, respectively, the gas constant and the absolute temperature. A plot of \(\ln \eta\) versus \(1 / T\) should be nearly linear, and with a slope of \(Q_{\text {vis }} / R\). Using the data in Figure 13.7, (a) make such a plot for the borosilicate glass, and (b) determine the activation energy between temperatures of 500 and \(900^{\circ} \mathrm{C}\).
Soda and lime are added to a glass batch in the form of soda ash \(\left(\mathrm{Na}_{2} \mathrm{CO}_{3}\right)\) and limestone \(\left(\mathrm{CaCO}_{3}\right)\). During heating, these two ingredients decompose to give off carbon dioxide \(\left(\mathrm{CO}_{2}\right)\), the resulting products being soda and lime. Compute the weight of soda ash and limestone that must be added to \(100 \mathrm{lb}_{\mathrm{m}}\) of quartz \(\left(\mathrm{SiO}_{2}\right.\) ) to yield a glass of composition \(75 \mathrm{wt} \% \mathrm{SiO}_{2}, 15 \mathrm{wt} \% \mathrm{Na}_{2} \mathrm{O}\), and \(10 \mathrm{wt} \% \mathrm{CaO}\).
From a molecular perspective, briefly explain the mechanism by which clay minerals become hydroplastic when water is added.
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