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Problem 6.6 Let the two "good" unperturbed states be

ψ±0=α±ψa0+β±ψb0

whereα±andβ±are determined (up to normalization) by Equation 6.22(orEquation6.24). Show explicitly that

(a)are orthogonal;role="math" localid="1655966589608" (⟨ψ+0∣ψ-0⟩=0);

(b) ⟨ψ+0|H'|ψ-0⟩=0;

(c)⟨ψ±0|H'|ψ±0⟩=E±1,withE±1given by Equation 6.27.

Short Answer

Expert verified

a) It is shown explicitly that⟨ψ+0∣ψ-0⟩=0

b) It is shown explicitly that⟨ψ+0|H'|ψ-0⟩=0

c) It is shown explicitly thatrole="math" localid="1655967130676" ⟨ψ±0|H'|ψ±0⟩=E±1

Step by step solution

01

Show ψ±0 are orthogonal (⟨ψ+0∣ψ-0⟩=0)

Two vectors are orthogonal in Euclidean space if and only if their dot product is zero, i.e. they form a 90° (/2 radian) angle, or one of the vectors is zero.

In this problem show that for

ψ±0=α±ψa0+β±ψb0

where

α±Waa+β±Wab=α±E±1α±Wba+β±Wbb=β±E±1E±1=12Waa+Wbb±(Waa-Wbb)2+4|Wab|2

Its given that

⟨ψ+0∣ψ-0⟩=0

This gives

⟨ψ+0∣ψ-0⟩=(α+*ψa0|+β-*⟨ψb0|)(α-|ψa0⟩+β-|ψb0⟩)⟩=α-*α++β-*β+

where it has been used⟨ψa0∣ψb0⟩=0=⟨ψb0∣ψa0⟩ and⟨ψa0∣ψa0⟩=1=⟨ψb0∣ψb0⟩ .

Now use the relation

β±=α±(E±1-Waa)/Wab

which gives

⟨ψ+0∣ψ-0⟩=α-*α+1+(E+1-Waa)(E-1-Waa)|Wab|2

The numerator in the second term is equal to

14Waa-Wbb+(Waa-Wbb)2+4|Wab|2Waa-Wbb-(Waa-Wbb)2+4|Wab|2=14((Waa-Wbb)2-(Waa-Wbb)2-4|Wab|2)=-|Wab|2

which gives

⟨ψ+0∣ψ-0⟩=(α-*α+)|Wab|2(|Wab|2-|Wab|2)=0

The states ψ±0are orthogonal.

02

Show that ⟨ψ+0|H'|ψ-0⟩=0

Now show that

⟨ψ+0|H'|ψ-0⟩=0

It is given that

⟨ψ+0|H'|ψ-0⟩=α+*α-⟨ψa0|H'|ψa0⟩+α+*β-⟨ψa0|H'|ψb0⟩+β+*α-⟨ψb0|H'|ψa0⟩+β+*β-⟨ψb0|H'|ψb0⟩=α+*α-Waa+α+*β-Wab+β+*α-Wba+β+*β-Wbb=α+*α-Waa+WabE-1-WaaWab+WbaE+1-WaaWba+Wbb(E+1-Waa)Wba(E-1-Waa)Wab=α+*α-Waa+E-1-Waa+E+1-Waa+Wbb(E+1-Waa)(E-1-Waa|Wab|2=α+*α-Waa+Wbb-Waa+Wbb-|Wab|2|Wab|2=0

03

Show that ⟨ψ±0|H'|ψ±0⟩=E±1

Now calculate⟨ψ±0|H'|ψ±0⟩

This gives

⟨ψ±0|H'|ψ±0⟩=α±*α±⟨ψa0|H'|ψa0⟩+α±*β±⟨ψa0|H'|ψb0⟩+β±*α±⟨ψb0|H'|ψa0⟩+β±*β±⟨ψb0|H'|ψb0⟩=|α±|2Waa+Wab(E±1-Waa)Wab+|β±|2Wba(E±1-Wbb)Wba+Wbb=|α±|2E±1+|β±|2E±1=(|α±|2+|β±|2)E±1=E±1

where this relation has been used.

role="math" localid="1655972198230" α±=β±(E±-Wbb)/Wba

in the second equality, and the fact that the sum of all probabilities is equal to one

|α±|2+|β±|2=1.

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Most popular questions from this chapter

Suppose we put a delta-function bump in the center of the infinite square well:

H'=αδ(x-a/2)

whereais a constant.

(a) Find the first-order correction to the allowed energies. Explain why the energies are not perturbed for evenn.

(b) Find the first three nonzero terms in the expansion (Equation 6.13) of the correction to the ground state,Ψ11.

If I=0, then j=s,mj=ms, and the "good" states are the same (nms)for weak and strong fields. DetermineEz1(from Equation) and the fine structure energies (Equation 6.67), and write down the general result for the I=O Zeeman Effect - regardless of the strength of the field. Show that the strong field formula (Equation 6.82) reproduces this result, provided that we interpret the indeterminate term in square brackets as.

Question: Consider the Stark effect (Problem 6.36) for the states of hydrogen. There are initially nine degenerate states, ψ3/m (neglecting spin, as before), and we turn on an electric field in the direction.

(a) Construct the matrix representing the perturbing Hamiltonian. Partial answer: <300|z|310>=-36a,<310|z|320>=-33a,<31±1|z|32±1>=-(9/2)a,,

(b) Find the eigenvalues, and their degeneracies.

Prove Kramers' relation:

sn2⟨rs⟩-(2s+1)a⟨rs-1⟩+s4[(2l+1)2-s2]a2⟨rs-2⟩=0

Which relates the expectation values of rto three different powers (s,s-1,ands-2),for an electron in the state ψn/mof hydrogen. Hint: Rewrite the radial equation (Equation) in the form

u''=[l(l+1)r2-2ar+1n2a2]u

And use it to expressrole="math" localid="1658192415441" ∫(ursu'')drin terms of (rs),(rs-1)and(rs-2). Then use integration by parts to reduce the second derivative. Show that ∫(ursu'')dr=-(s/2)(rs-1)and∫(u'rsu')dr=-[2/s+1]∫(u''rs+1u')dr. Take it from there.

(a) Find the second-order correction to the energies(En2)for the potential in Problem 6.1. Comment: You can sum the series explicitly, obtaining -for odd n.

(b) Calculate the second-order correction to the ground state energy(E02)for the potential in Problem 6.2. Check that your result is consistent with the exact solution.

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