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Problem 6.6 Let the two "good" unperturbed states be

ψ±0=α±ψa0+β±ψb0

whereα±andβ±are determined (up to normalization) by Equation 6.22(orEquation6.24). Show explicitly that

(a)are orthogonal;role="math" localid="1655966589608" (⟨ψ+0∣ψ-0⟩=0);

(b) ⟨ψ+0|H'|ψ-0⟩=0;

(c)⟨ψ±0|H'|ψ±0⟩=E±1,withE±1given by Equation 6.27.

Short Answer

Expert verified

a) It is shown explicitly that⟨ψ+0∣ψ-0⟩=0

b) It is shown explicitly that⟨ψ+0|H'|ψ-0⟩=0

c) It is shown explicitly thatrole="math" localid="1655967130676" ⟨ψ±0|H'|ψ±0⟩=E±1

Step by step solution

01

Show ψ±0 are orthogonal (⟨ψ+0∣ψ-0⟩=0)

Two vectors are orthogonal in Euclidean space if and only if their dot product is zero, i.e. they form a 90° (/2 radian) angle, or one of the vectors is zero.

In this problem show that for

ψ±0=α±ψa0+β±ψb0

where

α±Waa+β±Wab=α±E±1α±Wba+β±Wbb=β±E±1E±1=12Waa+Wbb±(Waa-Wbb)2+4|Wab|2

Its given that

⟨ψ+0∣ψ-0⟩=0

This gives

⟨ψ+0∣ψ-0⟩=(α+*ψa0|+β-*⟨ψb0|)(α-|ψa0⟩+β-|ψb0⟩)⟩=α-*α++β-*β+

where it has been used⟨ψa0∣ψb0⟩=0=⟨ψb0∣ψa0⟩ and⟨ψa0∣ψa0⟩=1=⟨ψb0∣ψb0⟩ .

Now use the relation

β±=α±(E±1-Waa)/Wab

which gives

⟨ψ+0∣ψ-0⟩=α-*α+1+(E+1-Waa)(E-1-Waa)|Wab|2

The numerator in the second term is equal to

14Waa-Wbb+(Waa-Wbb)2+4|Wab|2Waa-Wbb-(Waa-Wbb)2+4|Wab|2=14((Waa-Wbb)2-(Waa-Wbb)2-4|Wab|2)=-|Wab|2

which gives

⟨ψ+0∣ψ-0⟩=(α-*α+)|Wab|2(|Wab|2-|Wab|2)=0

The states ψ±0are orthogonal.

02

Show that ⟨ψ+0|H'|ψ-0⟩=0

Now show that

⟨ψ+0|H'|ψ-0⟩=0

It is given that

⟨ψ+0|H'|ψ-0⟩=α+*α-⟨ψa0|H'|ψa0⟩+α+*β-⟨ψa0|H'|ψb0⟩+β+*α-⟨ψb0|H'|ψa0⟩+β+*β-⟨ψb0|H'|ψb0⟩=α+*α-Waa+α+*β-Wab+β+*α-Wba+β+*β-Wbb=α+*α-Waa+WabE-1-WaaWab+WbaE+1-WaaWba+Wbb(E+1-Waa)Wba(E-1-Waa)Wab=α+*α-Waa+E-1-Waa+E+1-Waa+Wbb(E+1-Waa)(E-1-Waa|Wab|2=α+*α-Waa+Wbb-Waa+Wbb-|Wab|2|Wab|2=0

03

Show that ⟨ψ±0|H'|ψ±0⟩=E±1

Now calculate⟨ψ±0|H'|ψ±0⟩

This gives

⟨ψ±0|H'|ψ±0⟩=α±*α±⟨ψa0|H'|ψa0⟩+α±*β±⟨ψa0|H'|ψb0⟩+β±*α±⟨ψb0|H'|ψa0⟩+β±*β±⟨ψb0|H'|ψb0⟩=|α±|2Waa+Wab(E±1-Waa)Wab+|β±|2Wba(E±1-Wbb)Wba+Wbb=|α±|2E±1+|β±|2E±1=(|α±|2+|β±|2)E±1=E±1

where this relation has been used.

role="math" localid="1655972198230" α±=β±(E±-Wbb)/Wba

in the second equality, and the fact that the sum of all probabilities is equal to one

|α±|2+|β±|2=1.

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Most popular questions from this chapter

(a) Find the second-order correction to the energies(En2)for the potential in Problem 6.1. Comment: You can sum the series explicitly, obtaining -for odd n.

(b) Calculate the second-order correction to the ground state energy(E02)for the potential in Problem 6.2. Check that your result is consistent with the exact solution.

Estimate the correction to the ground state energy of hydrogen due to the finite size of the nucleus. Treat the proton as a uniformly charged spherical shell of radius b, so the potential energy of an electron inside the shell is constant:-e2/(4πϵ0b);this isn't very realistic, but it is the simplest model, and it will give us the right order of magnitude. Expand your result in powers of the small parameter, (b / a) whereis the Bohr radius, and keep only the leading term, so your final answer takes the form Δ·¡E=A(b/a)n. Your business is to determine the constant Aand the power n. Finally, put in b≈10-15m(roughly the radius of the proton) and work out the actual number. How does it compare with fine structure and hyperfine structure?

Suppose we put a delta-function bump in the center of the infinite square well:

H'=αδ(x-a/2)

whereais a constant.

(a) Find the first-order correction to the allowed energies. Explain why the energies are not perturbed for evenn.

(b) Find the first three nonzero terms in the expansion (Equation 6.13) of the correction to the ground state,Ψ11.

Suppose the Hamiltonian H, for a particular quantum system, is a function of some parameter λlet En(λ)and ψn(λ)be the eigen values and

Eigen functions of. The Feynman-Hellmann theorem22states that

∂En∂λ=(ψn∂H∂λψn)

(Assuming either that Enis nondegenerate, or-if degenerate-that the ψn's are the "good" linear combinations of the degenerate Eigen functions).

(a) Prove the Feynman-Hellmann theorem. Hint: Use Equation 6.9.

(b) Apply it to the one-dimensional harmonic oscillator,(i)using λ=Ӭ(this yields a formula for the expectation value of V), (II)using λ=ħ(this yields (T)),and (iii)using λ=m(this yields a relation between (T)and (V)). Compare your answers to Problem 2.12, and the virial theorem predictions (Problem 3.31).

Consider the isotropic three-dimensional harmonic oscillator (Problem 4.38). Discuss the effect (in first order) of the perturbation H'=λ³æ2yz

(for some constant λ) on

(a) the ground state

(b) the (triply degenerate) first excited state. Hint: Use the answers to Problems 2.12and 3.33

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