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Chapter 6: Time-Independent Perturbation Theory

Q3P

Page 255

Two identical spin-zero bosons are placed in an infinite square well (Equation 2.19). They interact weakly with one another, via the potential

V(x1,x2)=-aV0(x1-x2). (2.19).

(where V0is a constant with the dimensions of energy, and a is the width of the well).

(a)First, ignoring the interaction between the particles, find the ground state and the first excited state鈥攂oth the wave functions and the associated energies.

(b) Use first-order perturbation theory to estimate the effect of the particle鈥 particle interaction on the energies of the ground state and the first excited state.

Q4P

Page 256

(a) Find the second-order correction to the energies(En2)for the potential in Problem 6.1. Comment: You can sum the series explicitly, obtaining -for odd n.

(b) Calculate the second-order correction to the ground state energy(E02)for the potential in Problem 6.2. Check that your result is consistent with the exact solution.

Q5P

Page 256

Consider a charged particle in the one-dimensional harmonic oscillator potential. Suppose we turn on a weak electric field (E), so that the potential energy is shifted by an amountH'=-qEx.(a) Show that there is no first-order change in the energy levels, and calculate the second-order correction. Hint: See Problem 3.33.

(b) The Schr枚dinger equation can be solved directly in this case, by a change of variablesx'x-(qE/尘蝇2). Find the exact energies, and show that they are consistent with the perturbation theory approximation.

Q6P

Page 260

Problem 6.6 Let the two "good" unperturbed states be

0=a0+b0

whereandare determined (up to normalization) by Equation 6.22(orEquation6.24). Show explicitly that

(a)are orthogonal;role="math" localid="1655966589608" (+0-0=0);

(b) +0|H'|-0=0;

(c)0|H'|0=E1,withE1given by Equation 6.27.

Q7P

Page 260

Consider a particle of mass m that is free to move in a one-dimensional region of length L that closes on itself (for instance, a bead that slides frictionlessly on a circular wire of circumference L, as inProblem 2.46).

(a) Show that the stationary states can be written in the formn(x)=1Le2inx/L,(-L/2<x<L/2),

wheren=0,1,2,....and the allowed energies areEn=2mnL2.Notice that with the exception of the ground state (n = 0 ) 鈥 are all doubly degenerate.

(b) Now suppose we introduce the perturbation,H'=-V0e-x2/a2where aLa. (This puts a little 鈥渄imple鈥 in the potential at x = 0, as though we bent the wire slightly to make a 鈥渢rap鈥.) Find the first-order correction to En, using Equation 6.27. Hint: To evaluate the integrals, exploit the fact that aLato extend the limits from L/2toafter all, H鈥 is essentially zero outside -a<x<a.

E1=12Waa+WbbWaa-Wbb2+4Wab2(6.27).

(c) What are the 鈥済ood鈥 linear combinations ofnand-n, for this problem? Show that with these states you get the first-order correction using Equation 6.9.

En'=n0H'n0(6.9).

(d) Find a hermitian operator A that fits the requirements of the theorem, and show that the simultaneous Eigenstates ofH0and A are precisely the ones you used in (c).

Q8P

Page 265

Suppose we perturb the infinite cubical well (Equation 6.30) by putting a delta function 鈥渂ump鈥 at the point(a/4,a/2,3a/4):H'=a3V0(x-a/4)(y-a/2)(z-3a/4).

Find the first-order corrections to the energy of the ground state and the (triply degenerate) first excited states.

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