/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Q7P Calculate d〈p〉/dt. Answer:d... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

Calculate d〈p〉/dt. Answer:

dpdx=-∂V∂x

This is an instance of Ehrenfest’s theorem, which asserts that expectation values obey the classical laws

Short Answer

Expert verified

dpdx=-∂V∂x

Schrodinger equation and its complex conjugate:

role="math" localid="1657778797745" ∂ψ∂t=ih2m∂2ψ∂x2-ihVx,tψx,t1∂ψ*∂t=-ih2m∂2ψ*∂x2+ihVx,tψx,t2

And according to Ehrenfest’s theorem,

p=mv=mdxdt

Step by step solution

01

Determining the expectation value of x

Finding the expectation values.

x=∫-∞∞xψx.t2dx∫-∞∞ψx.t2dxx=∫-∞∞xψx.t2dxx=∫-∞∞ψx.tψ*x.tdxx=∫-∞∞ψx.tψ*x.tdx

02

Differentiating both the sides with respect to t,

dxdt=∫-∞∞ψx.tψx*x.tdxdxdt=∫-∞∞×∂ψ∂tψx.tψ*x.tdxdxdt=∫-∞∞×∂ψ∂tψ+ψ*∂ψ∂tdx

03

Now, substituting the Schrodinger equation for the time derivatives

∫-∞∞X-ih2m∂2ψ*∂xψ+ihVψ*ψ+ih2mψ*∂2ψ∂x2-ihVψ*ψdx

dxdt=ih2m∫-∞∞×ψ*∂2ψ∂x2-∂2ψ*∂x2ψdx

dxdt=ih2m∫-∞∞×∂ψ*∂x∂ψ∂x2+ψ*∂2ψ2∂x2-∂2ψ2∂x2ψ+∂ψ*∂x∂ψ∂xdx

role="math" localid="1657786380532" dxdt=ih2m∫-∞∞×∂∂xψ*∂ψ∂x-∂∂x∂ψ*∂xψdx

dxdt=ih2m∫-∞∞×∂∂xψ*∂ψ∂x-∂∂x∂ψ*∂xψdxdxdt=ih2m×ψ*ψ-∞∞-∫-∞∞ψ*∂ψ∂xdx-∫-∞∞ψ*∂ψ∂xdxdxdt=ih2m∫-∞∞ψ*∂ψ∂xdx

Now, multiplying both sides by m

mdxdt=-ih∫-∞∞ψ*∂ψ∂xdx

And using equation (3)

p=-ih∫-∞∞ψ*∞∂ψ∂xdxp=∫-∞∞ψ*-ih∂∂xψdx

04

Differentiating both the sides with respect to t

We get the desired value,

dpdt=-ihddt∫-∞∞ψ*∂ψ∂xdxdpdt=-ih∫-∞∞ψ*∂ψ∂xdx
05

Using Clairaut’s theorem and substituting equation (1) and (2)

We get,

dpdt=-ih∫-∞∞∂ψ*∂t∂ψ∂t+ψ*∂∂x∂ψ∂tdxdpdt=-ih∫-∞∞-ih2m∂2ψ∂x2+ihVψ*∂ψ∂x+ψ*∂∂xih2m∂2ψ∂x2+ihVψdx
dpdt=-ih∫-∞∞-ih2m∂2ψ∂x2∂ψ∂x+ihVψ*∂ψ∂xih2mψ*∂3ψ∂x3-ih∂V∂xψ*ψ-ihVψ*∂ψ∂xdpdt=-ih--ih2m∂ψ*∂x∂ψ∂x-∫-∞∞∂ψ∂x∂2ψ∂x2dx+∫-∞∞ih2mψ∂3ψ∂x3-ih∂V∂xψ*ψdx

localid="1657947924145" dpdt=-ih∫-∞∞-ih2mψ*∂3ψ∂x+ih2mψ*∂3∂x3-ih∂V∂Xψ*ψdxdpdt=i2∫-∞∞∂V∂Xψ*ψdx

dpdt=i2∫-∞∞∂V∂xψ*ψdx

dpdt=-∫-∞∞∂v∂xψ*ψdxdpdt=∫-∞∞ψ*-∂V∂xψdxdpdt=-∂V∂x

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

In general, quantum mechanics is relevant when the de Broglie wavelength of the principle in question(h/p)is greater than the characteristic Size of the system (d). in thermal equilibrium at (kelvin) TemperatureTthe average kinetic energy of a particle is

p22m=32kBT

(Where kBis Boltzmann's constant), so the typical de Broglie wavelength is

λ=h3mkBT

The purpose of this problem is to anticipate which systems will have to be treated quantum mechanically, and which can safely be described classically.

(a) Solids. The lattice spacing in a typical solid is around d=0.3nm. Find the temperature below which the free 18electrons in a solid are quantum mechanical. Below what temperature are the nuclei in a solid quantum mechanical? (Use sodium as a typical case.) Moral: The free electrons in a solid are always quantum mechanical; the nuclei are almost never quantum mechanical. The same goes for liquids (for which the interatonic spacing is roughly the same), with the exception of helium below 4K.

(b) Gases. For what temperatures are the atoms in an ideal gas at pressure Pquantum mechanical? Hint: Use the ideal gas law(PV=NkBT)to deduce the interatomic spacing.

We consider the same device as the previous problem, but this time we are interested in thex-coordinate of the needle point-that is, the "shadow," or "projection," of the needle on the horizontal line.

(a) What is the probability density ÒÏ(x)? Graph data-custom-editor="chemistry" ÒÏ(x) as a function of x, from -2rto +2r , where ris the length of the needle. Make sure the total probability is . Hint: data-custom-editor="chemistry" ÒÏ(x)dx is the probability that the projection lies between data-custom-editor="chemistry" xand data-custom-editor="chemistry" (x+dx). You know (from Problem 1.11) the probability that data-custom-editor="chemistry" θ is in a given range; the question is, what interval data-custom-editor="chemistry" dxcorresponds to the interval data-custom-editor="chemistry" »åθ?

(b) Compute data-custom-editor="chemistry" <x>, data-custom-editor="chemistry" <x2>, and data-custom-editor="chemistry" σ, for this distribution. Explain how you could have obtained these results from part (c) of Problem 1.11.

Consider the first 25 digits in the decimal expansion of π (3, 1, 4, 1, 5, 9, . . .).

(a) If you selected one number at random, from this set, what are the probabilities of getting each of the 10 digits?

(b) What is the most probable digit? What is the median digit? What is the average value?

(c) Find the standard deviation for this distribution.

(a) Find the standard deviation of the distribution in Example 1.1.

(b) What is the probability that a photograph, selected at random, would show a distance x more than one standard deviation away from the average?

For the distribution of ages in the example in Section 1.3.1:

(a) Compute⟨j2⟩ and⟨j⟩2 .

(b) Determine ∆j for each j, and use Equation 1.11 to compute the standard deviation.

(c) Use your results in (a) and (b) to check Equation 1.12.

See all solutions

Recommended explanations on Physics Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.