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Why can鈥檛 you do integration-by-parts directly on the middle expression in Equation -1.29 pull the time derivative over onto x, note thatx/t=0 , and conclude thatd<x>/dt=0 ?

Short Answer

Expert verified

Because the derivative and integrals are taken with respect to different variables t and x,so the integration-by-parts is not possible.

Step by step solution

01

The given information

The equation 1.29 is,

dxdt=xt2dx=ih2mxt*t-*tdx

According to the given question, X/T=0. Integration-by-parts directly cannot be done on the middle expression dxdt=xt2dx=ih2mxt*t-*tdx.

02

The expected equation and the variables.

The expected value is the average of the results of a large number of measurements taken on separate systems.

The following is the expression for X's expected value:

X=*x,txx,tdxX=xx,t2dx

The wave function is x,t, and the average value or expectation value of the position operator x is x.

03

The differentiate of the equation and put the value of  x

The above equation have to be differentiated on both sides:

dxdt=xt2dx

The time derivative will be put on to xas the condition is given. So, the equation is:

dxdt=xtx2dx=t2dx+xt2dx=0+xt2dx=xt2dx

04

The limit of the equation

Taking the above equation in between aand b,the equation will be:

dxdt=batx2dx=x2dxab

The derivative is with regard to time, while the integration is with respect toxin the above integration.

As a result, part-by-part integration is not possible.

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Most popular questions from this chapter

Calculate d銆坧銆/dt. Answer:

dpdx=-Vx

This is an instance of Ehrenfest鈥檚 theorem, which asserts that expectation values obey the classical laws

A particle of mass m is in the state:

(x,t)=Aea[(mx2/h)+it]

where A and a are positive real constants.

(a) Find A.

(b) For what potential energy function, V(x), is this a solution to the Schr枚dinger equation?

(c) Calculate the expectation values of x,x2 , p, andp2 .

(d) Find 蟽x and 蟽p. Is their product consistent with the uncertainty principle?

We consider the same device as the previous problem, but this time we are interested in thex-coordinate of the needle point-that is, the "shadow," or "projection," of the needle on the horizontal line.

(a) What is the probability density (x)? Graph data-custom-editor="chemistry" (x) as a function of x, from -2rto +2r , where ris the length of the needle. Make sure the total probability is . Hint: data-custom-editor="chemistry" (x)dx is the probability that the projection lies between data-custom-editor="chemistry" xand data-custom-editor="chemistry" (x+dx). You know (from Problem 1.11) the probability that data-custom-editor="chemistry" is in a given range; the question is, what interval data-custom-editor="chemistry" dxcorresponds to the interval data-custom-editor="chemistry" 诲胃?

(b) Compute data-custom-editor="chemistry" <x>, data-custom-editor="chemistry" <x2>, and data-custom-editor="chemistry" , for this distribution. Explain how you could have obtained these results from part (c) of Problem 1.11.

Suppose you add a constantV0 to the potential energy (by 鈥渃onstant鈥 I mean independent ofxas well as t). In classical mechanics this doesn鈥檛 change anything, but what about quantum mechanics? Show that the wave function picks up a time-dependent phase factor:exp(-iV0t/h). What effect does this have on the expectation value of a dynamical variable?

In general, quantum mechanics is relevant when the de Broglie wavelength of the principle in question(h/p)is greater than the characteristic Size of the system (d). in thermal equilibrium at (kelvin) TemperatureTthe average kinetic energy of a particle is

p22m=32kBT

(Where kBis Boltzmann's constant), so the typical de Broglie wavelength is

=h3mkBT

The purpose of this problem is to anticipate which systems will have to be treated quantum mechanically, and which can safely be described classically.

(a) Solids. The lattice spacing in a typical solid is around d=0.3nm. Find the temperature below which the free 18electrons in a solid are quantum mechanical. Below what temperature are the nuclei in a solid quantum mechanical? (Use sodium as a typical case.) Moral: The free electrons in a solid are always quantum mechanical; the nuclei are almost never quantum mechanical. The same goes for liquids (for which the interatonic spacing is roughly the same), with the exception of helium below 4K.

(b) Gases. For what temperatures are the atoms in an ideal gas at pressure Pquantum mechanical? Hint: Use the ideal gas law(PV=NkBT)to deduce the interatomic spacing.

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