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As an explicit example of the method developed inProblem 7.15, consider an electron at rest in a uniform magnetic field B=B2kfor which the Hamiltonian is (Equation 4.158):

H=-纬叠 (4.158).

H0=eBzmSz (7.57).

The eigenspinors, xaarelocalid="1655969802629" xb,andthecorrespondingenergies,EaandEb,aregiven in Equation 4.161. Now we turn on a perturbation, in the form of a uniform field in the x direction:

{x+,withenergyE+=-B0/2x-,withenergyE-=+-B0/2 (4.161).

H'=eBxmSx (7.58).

(a) Find the matrix elements of H鈥, and confirm that they have the structure of Equation 7.55. What is h?

(b) Using your result inProblem 7.15(b), find the new ground state energy, in second-order perturbation theory.

(c) Using your result inProblem 7.15(c), find the variation principle bound on the ground state energy.

Short Answer

Expert verified

(a)<xa|H'|xb>=eBx2m(01)(0110)(10)=eBx2m(01)(01)=eBx2m.soh=eBx2m.

(b) EgsEa-h2(Eb-Ea)=e2m(Bz+Bx22Bz).

(c) Egs=-12(eBzm)2+4(eBzm)2=-e2mB2z+B2z.

Step by step solution

01

(a)Finding the matrix elements of H'

For the electron, . (Eq. 4.161).

For consistency with Problem 7.15,

soxbx+=10,xa=x-=01,Eb=Ex=eBz2m,Ea=E-=-eBz2m.

x+,withenergyE+=-B0/2x-,withenergyE-=+纬叠0/2

|xaH'xa=ebxm201011001=ebx2m0110.xbH'xb=ebx2m10011010=0,.xbH'xb=ebx2m10011001=ebx2m101010.xbH'xb=ebx2m01011010=ebx2m0101=ebx2m.andtheconditionsofProblem7.15aremet.

02

(b)Finding the new ground state energy

From Problem 7.15(b),

EgsEa-h2EbEa=-eBx2m-eBx/2m2(eBx/m)=-e2mBz+Bx22Bz.

03

(c)Finding the variation principle bound

From Problem 7.15(c),

Egs=12Ea+Ea-Eb-Ea2+4h2,(itsactuallytheexactgroundstate).Egs=12eBzm2+4eBzm2=-e2mBz2+Bx2.whichwasobviousfromthestart,sincethesquarerootissimplythemagnitudeofthetotalfield).

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Most popular questions from this chapter

Apply the techniques of this Section to the H-and Li+ions (each has two electrons, like helium, but nuclear charges Z=1and Z=3, respectively). Find the effective (partially shielded) nuclear charge, and determine the best upper bound on Egs, for each case. Comment: In the case of H- you should find that (H)>-13.6eV, which would appear to indicate that there is no bound state at all, since it would be energetically favourable for one electron to fly off, leaving behind a neutral hydrogen atom. This is not entirely surprising, since the electrons are less strongly attracted to the nucleus than they are in helium, and the electron repulsion tends to break the atom apart. However, it turns out to be incorrect. With a more sophisticated trial wave function (see Problem 7.18) it can be shown that Egs<-13.6eVand hence that a bound state does exist. It's only barely bound however, and there are no excited bound states, soH- has no discrete spectrum (all transitions are to and from the continuum). As a result, it is difficult to study in the laboratory, although it exists in great abundance on the surface of the sun.

Suppose you鈥檙e given a two-level quantum system whose (time-independent) Hamiltonian H0admits just two Eigen states, a (with energy Ea ), and b(with energy Eb ). They are orthogonal, normalized, and non-degenerate (assume Ea is the smaller of the two energies). Now we turn on a perturbation H鈥, with the following matrix elements:

a|H'|a=b|H'|b=0;a|H'|b=b|H'|a (7.74).

where h is some specified constant.

(a) Find the exact Eigen values of the perturbed Hamiltonian.

(b) Estimate the energies of the perturbed system using second-order perturbation theory.

(c) Estimate the ground state energy of the perturbed system using the variation principle, with a trial function of the form

=(肠辞蝉蠒)a+(蝉颈苍蠒)b (7.75).

where 蠒 is an adjustable parameter. Note: Writing the linear combination in this way is just a neat way to guarantee that 蠄 is normalized.

(d) Compare your answers to (a), (b), and (c). Why is the variational principle so accurate, in this case?

(a) Use a trial wave function of the form

(x)={Acos(x/a),if(a/2<x<a/2)0otherwise

to obtain a bound on the ground state energy of the one-dimensional harmonic oscillator. What is the "best" value ofa? CompareHminwith the exact energy. Note: This trial function has a "kink" in it (a discontinuous derivative) ata/2; do you need to take account of this, as I did in Example 7.3?

(b) Use(x)=Bsin(x/a)on the interval(a,a)to obtain a bound on the first excited state. Compare the exact answer.

If the photon had a nonzero mass m0, the Coulomb potential would be replaced by the Yukawa potential,

V(r)=-e240e-rr (8.73).

Where=mc/ . With a trial wave function of your own devising, estimate the binding energy of a 鈥渉ydrogen鈥 atom with this potential. Assumea1 , and give your answer correct to order(a)2 .

(a) Prove the following corollary to the variational principle: If gs=0then谩贬帽Efe whereEfe is the energy of the first excited state. Comment: If we can find a trial function that is orthogonal to the exact ground state, we can get an upper bound on the first excited state. In general, it's difficult to be sure that is orthogonal togsi since (presumably) we don't know the latter. However, if the potentialV(x) is an even function of x, then the ground state is likewise even, and hence any odd trial function will automatically meet the condition for the corollary.

(b) Find the best bound on the first excited state of the one-dimensional harmonic oscillator using the trial function(x)=Axe-bx2

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