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Coincident spectral lines. 43According to the Rydberg formula (Equation 4.93) the wavelength of a line in the hydrogen spectrum is determined by the principal quantum numbers of the initial and final states. Find two distinct pairs{ni,nf} that yield the same . For example,role="math" localid="1656311200820" {6851,6409} and{15283,11687}will do it, but you're not allowed to use those!

Short Answer

Expert verified

The two distinct pairs ni,nfthat yield the same is 35,25175,35

Step by step solution

01

Determine the Rydberg formula

The Rydberg formula is a mathematical method for calculating light wavelength. The energy of an electron varies when it moves from one atomic orbit to another.

1=R1nf21ni2

02

Determine the two distinct pairs

Out mission in this problem is to find the four numbers such that they produce the same spectral lines.

According to the Rydberg formula:

1=R1nf21ni2

It is very difficult to just guess some values.

The given numbers to find new numbers, the given pair of numbers are 6851,6409and 15283,11687.

For these two pairs, find their prime factors:

6851=1317316409=13172915283=17293111687=132931

The first pair of numbers have two common factors and also the second pair have two common factors, where each member of the first pair uses one of the prime factors of the second pair, and vice versa.

The numbers can be written as:

164092-168512=1116872-115283211317292-11317312=11329312-11729312Leta=31,b=29,c=17andd=13,thenwecanwrite:1bcd2-1acd2=1abd2-1abc2a2-b2abcd2=c2-d2abcd2a2-b2=c2-d2a+ba-b=c+dc-d

The method is to choose two prime numbers a and b, then we find the difference a2-b2after that we find the factors of the difference, from these factors we take two number and such thatc+dc-d=a2-b2

Let a=7and b=5then a2-b2=24which has factors of 1,2,3, 6,8 and 12 note that we have already used 2 and 12

Therefore a+b=12and a-b=2we pick another two numbers, say, 4 and 6 , that is:

c=5c+d=65+d=6d=6-5d=1

Substitute d=1in the above equation

c-d=4c-1=4c=4+1c=5

But :

1bcd2-1acd2=1abd2-1abc2

where the pairs are bcd,acdand abd,abc,so:

1252-1352=1352-11752

So the pairs are:

35,25175,35

Follow this method to find another pairs but you have to be careful, since not all the numbers work using this method, so you have to check your pairs.

Therefore, the two distinct pairs ni,nfthat yield the same is35,25175,35

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Most popular questions from this chapter

(a) Using Equation 4.88, work out the first four Laguerre polynomials.

(b) Using Equations 4.86, 4.87, and 4.88, find v(), for the case n=5,I=2.

(c) Find v()again (for the case role="math" localid="1658315521558" n=5,I=2), but this time get it from the recursion formula (Equation 4.76).

Lq(x)=eqq!(ddx)q(e-x-x9)(4.88)v()=Ln-2l+1l-1(4.86)Lqp(x)(-1)pddxLp+q(x)(4.87)cj+1=2(j+l+1-n)(j+1)(j+2l+2)cj(4.76)

Use equations 4.27 4.28 and 4.32 to constructy00,y21Check that they are normalized and orthogonal

The fundamental commutation relations for angular momentum (Equation 4.99) allow for half-integer (as well as integer) eigenvalues. But for orbital angular momentum only the integer values occur. There must be some extra constraint in the specific formL=rp that excludes half-integer values. Let be some convenient constant with the dimensions of length (the Bohr radius, say, if we're talking about hydrogen), and define the operators

q112[x+a2/py];p112[px-(/a2)y];q212[x-(a2/)py];p212[px-(/a2)y];

(a) Verify that [q1,q2]=[p1,p2]=0;[q1,p1]=[p2,q2]=i. Thus the q's and the p's satisfy the canonical commutation relations for position and momentum, and those of index 1are compatible with those of index 2 .

(b) Show that[q1,q2]=[p1,p2]Lz=2a2(q12-q22)+a22(p12-p22)

(c) Check that , where each is the Hamiltonian for a harmonic oscillator with mass and frequency .

(d) We know that the eigenvalues of the harmonic oscillator Hamiltonian are , where (In the algebraic theory of Section this follows from the form of the Hamiltonian and the canonical commutation relations). Use this to conclude that the eigenvalues of must be integers.

(a) Construct the wave function for hydrogen in the state n=4,I=3,m=3. Express your answer as a function of the spherical coordinates r,and.

(b) Find the expectation value of role="math" localid="1658391074946" rin this state. (As always, look up any nontrivial integrals.)

(c) If you could somehow measure the observable Lx2+Ly2on an atom in this state, what value (or values) could you get, and what is the probability of each?

Use Equation 4.32 to construct Yll(,)andy32(.) . (You can take P32from Table 4.2, but you'll have to work outPll from Equations 4.27 and 4.28.) Check that they satisfy the angular equation (Equation 4.18), for the appropriate values of l and m .

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