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a) Check that the spin matrices (Equations 4.145 and 4.147) obey the fundamental commutation relations for angular momentum, Equation 4.134.

Sz=h2(100-1)(4.145).Sx=h2(0110),sy=h2(0-ii0)(4.147).[Sx,Sy]=ihSz,[Sy,Sz]=ihSx,[Sz,Sx]=ihSy(4.134).(b)ShowthatthePaulispinmatrices(Equation4.148)satisfytheproductruleσx≡(0110),σy≡(0-ii0),σz≡(100-1)(4.148).σjσk=δjk+i∑o'IjklσI,(4.153).

Wheretheindicesstandforx,y,orz,ando'jklistheLevi-Civitasymbol:+1ifjkl=123,231,or2=312;-1ifjkl=132,213,or321;otherwise.

Short Answer

Expert verified

(a)Sx,Sy=ihSz-(b)σjσk=δjk+i∑ojkl'σI-I

Step by step solution

01

(a) Checking the spin matrices obey the fundamental commutation relations for angular momentum.

The spin matrices are

Sz=h2100-1Sx=h20110,Sy=h20-ii0Sx,Sy=SxSy-SySx=h2201100-ii0-0-ii00110.=h24i00-i--i00i=h242i00-2i=ihh22100-1Sx,Sy=ihSz

02

(b) Showing the Pauli spin matrices satisfies the product rule.

σxσx=1001=1=σyσy=σzσz,Soσjσj=1forj=x,y,orz.σxσy=i00-i=iσz;σyσz=0ii0=iσx;σzσx=01-10=iσy.σyσx=-i00-i=iσz;σzσy=0-i-i0=-iσx;σxσz=0-110=-iσy.

Equation 4.153 packages all this in a single formula.

σjσk=δjk+i∑IojklσI.'

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Most popular questions from this chapter

The electron in a hydrogen atom occupies the combined spin and position stateR211/3Y10χ++2/3Y11χ-

(a) If you measured the orbital angular momentum squared L2, what values might you get, and what is the probability of each?

(b) Same for the component of orbital angular momentum Lz.

(c) Same for the spin angular momentum squaredS2 .

(d) Same for the component of spin angular momentum Sz.

Let J≡L+Sbe the total angular momentum.

(e) If you measureddata-custom-editor="chemistry" J2 , what values might you get, and what is the probability of each?

(f) Same forJz .

(g) If you measured the position of the particle, what is the probability density for finding it atr , θ,ϕ ?

(h) If you measured both the component of the spin and the distance from the origin (note that these are compatible observables), what is the probability density for finding the particle with spin up and at radius ?

A hydrogenic atom consists of a single electron orbiting a nucleus with Z protons. (Z=1 would be hydrogen itself,Z=2is ionized helium ,Z=3is doubly ionized lithium, and so on.) Determine the Bohr energies En(Z), the binding energyE1(Z), the Bohr radiusa(Z), and the Rydberg constant R(Z)for a hydrogenic atom. (Express your answers as appropriate multiples of the hydrogen values.) Where in the electromagnetic spectrum would the Lyman series fall, for Z=2and Z=3? Hint: There’s nothing much to calculate here— in the potential (Equation 4.52) Ze2, so all you have to do is make the same substitution in all the final results.

V(r)=-e24πo0˙1r (4.52).

What is the most probable value of r, in the ground state of hydrogen? (The answer is not zero!) Hint: First you must figure out the probability that the electron would be found between r and r + dr.

(a) Prove that for a particle in a potential V(r)the rate of change of the expectation value of the orbital angular momentum L is equal to the expectation value of the torque:

ddt<L>=<N>

Where,

N=r×(VV)

(This is the rotational analog to Ehrenfest's theorem.)

(b) Show that d<L>/dt=0for any spherically symmetric potential. (This is one form of the quantum statement of conservation of angular momentum.)

An electron is at rest in an oscillating magnetic field

B=B0cos(Ó¬³Ù)k^

whereB0 andÓ¬ are constants.

(a) Construct the Hamiltonian matrix for this system.

(b) The electron starts out (at t=0 ) in the spin-up state with respect to the x-axis (that is:χ(0)=χ+(x)). Determine X(t)at any subsequent time. Beware: This is a time-dependent Hamiltonian, so you cannot get in the usual way from stationary states. Fortunately, in this case you can solve the timedependent Schrödinger equation (Equation 4.162) directly.

(c) Find the probability of getting-h/2 , if you measure Sx. Answer:

sin2(γµþ02Ó¬sin(Ó¬³Ù))

(d) What is the minimum field(B0) required to force a complete flip inSx ?

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