Chapter 4: Q26P (page 177)
a) Check that the spin matrices (Equations 4.145 and 4.147) obey the fundamental commutation relations for angular momentum, Equation 4.134.
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Chapter 4: Q26P (page 177)
a) Check that the spin matrices (Equations 4.145 and 4.147) obey the fundamental commutation relations for angular momentum, Equation 4.134.
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The electron in a hydrogen atom occupies the combined spin and position state
(a) If you measured the orbital angular momentum squared , what values might you get, and what is the probability of each?
(b) Same for the component of orbital angular momentum .
(c) Same for the spin angular momentum squared .
(d) Same for the component of spin angular momentum .
Let be the total angular momentum.
(e) If you measureddata-custom-editor="chemistry" , what values might you get, and what is the probability of each?
(f) Same for .
(g) If you measured the position of the particle, what is the probability density for finding it at , , ?
(h) If you measured both the component of the spin and the distance from the origin (note that these are compatible observables), what is the probability density for finding the particle with spin up and at radius ?
A hydrogenic atom consists of a single electron orbiting a nucleus with Z protons. ( would be hydrogen itself,is ionized helium ,is doubly ionized lithium, and so on.) Determine the Bohr energies , the binding energy, the Bohr radius, and the Rydberg constant Rfor a hydrogenic atom. (Express your answers as appropriate multiples of the hydrogen values.) Where in the electromagnetic spectrum would the Lyman series fall, for and ? Hint: There’s nothing much to calculate here— in the potential (Equation 4.52) , so all you have to do is make the same substitution in all the final results.
(4.52).
What is the most probable value of r, in the ground state of hydrogen? (The answer is not zero!) Hint: First you must figure out the probability that the electron would be found between r and r + dr.
(a) Prove that for a particle in a potential V(r)the rate of change of the expectation value of the orbital angular momentum L is equal to the expectation value of the torque:
Where,
(This is the rotational analog to Ehrenfest's theorem.)
(b) Show that for any spherically symmetric potential. (This is one form of the quantum statement of conservation of angular momentum.)
An electron is at rest in an oscillating magnetic field
where and are constants.
(a) Construct the Hamiltonian matrix for this system.
(b) The electron starts out (at t=0 ) in the spin-up state with respect to the x-axis (that is:. Determine at any subsequent time. Beware: This is a time-dependent Hamiltonian, so you cannot get in the usual way from stationary states. Fortunately, in this case you can solve the timedependent Schrödinger equation (Equation 4.162) directly.
(c) Find the probability of getting , if you measure . Answer:
(d) What is the minimum field required to force a complete flip in ?
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