Chapter 4: Q26P (page 177)
a) Check that the spin matrices (Equations 4.145 and 4.147) obey the fundamental commutation relations for angular momentum, Equation 4.134.
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Chapter 4: Q26P (page 177)
a) Check that the spin matrices (Equations 4.145 and 4.147) obey the fundamental commutation relations for angular momentum, Equation 4.134.
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(a) Find〈r〉and〈r²〉for an electron in the ground state of hydrogen. Express your answers in terms of the Bohr radius.
(b) Find〈x〉and for an electron in the ground state of hydrogen.
Hint: This requires no new integration—note that ,and exploit the symmetry of the ground state.
(c) Find〈x²〉in the state . Hint: this state is not symmetrical in x, y, z. Use
Use equations 4.27 4.28 and 4.32 to construct Check that they are normalized and orthogonal
Because the three-dimensional harmonic oscillator potential (Equation 4.188)is spherically symmetric, the Schrödinger equation can be handled by separation of variables in spherical coordinates, as well as cartesian coordinates. Use the power series method to solve the radial equation. Find the recursion formula for the coefficients, and determine the allowed energies. Check your answer against Equation4.189.
(a) Apply tolocalid="1656131461017" (Equation), and confirm that you getlocalid="1656131442455" .
(b) Applyto(Equation), and confirm that you get zero.
(c) Show thatlocalid="1656131424007" andlocalid="1656131406083" (Equation) are eigenstates of, with the appropriate eigenvalue
(a) Normalize (Equation 4.82), and construct the function.
(b) Normalize(Equation 4.83), and construct the function.
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