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(a) What isL+Y1I? (No calculation allowed!)

(b) Use the result of (a), together with Equation 4.130 and the fact thatLzY1I=hIYII to determineYII(θ,ϕ) , up to a normalization constant.

(c) Determine the normalization constant by direct integration. Compare your final answer to what you got in Problem 4.5.

Short Answer

Expert verified

(a) The value of L+Y1Iis 0.

(b) The value of YII(θ,ϕ)is A sinθeiϕI.

(c) The normalization constant is 12I+1I!2I+1!Ï€.

Step by step solution

01

Normalization constant

A normalizing constant guarantees that the probability of a probability density function is 1. The constant can appear in many forms, including scalar values, equations, and even functions.

As a result, there is not a "one size fits all" constant; instead, any probability distribution that does not sum to 1 will have its own normalization constant.

02

(a) Determination of the value of the expression

The operator L+ is the raising operator that is acting on the function YIm. It gives a result proportional to YIm+1but the maximum value of m is I . So, YIIis the top function.

Thus, the value of L+YII is 0.

03

(b) Determination of the value of YII(θ,f)  

Consider LzYII=hIYIIand use the definition of Lzto solve for YII.

localid="1658204848834" LzY1I(θ,ϕ)=hIY1I(θ,ϕ)-ih∂Y1I(θ,ϕ)∂ϕ=hIY1I(θ,ϕ)∂Y1IY1I=iI∂ϕY1I(θ,ϕ)=f(θ)eiIϕ

It can be observed that from part (a) localid="1658204942389" L+YII=0. So, substitute 0 for L+YIIin the above expression.

L+fθeiIϕ=0

Unravele the definition.

he∂fθ∂θ.eiIϕ+icotθfθ∂eiIϕ∂ϕ=0∂fθ∂θ.eiIϕ+icotθfθileilϕ=0∂fθ∂θ=lcotθfθ

Integrate both sides of the above equation.

∫∂fθfθdθ=∫IcotθdθInfθ=lInsinθ+kInfθ=lInAsinIθfθ=AsinI(θ)YIIθ,ϕ=AsinIθeilϕ

Here, A isanormalization constant.

Thus, the value of YIIθ,ϕis A sinθeiϕl.

04

Step 4: (c) Determination of normalization constant

To normalize the function 1=∫YIIθ,ϕ2sinθdθdϕis required.

Substitute in AsinθeiϕIfor YIIin the expression.

1=A2∫02π∫0πsin2Iθsinθdθdϕ=2πA2∫0πsin2Iθsinθdθ=2πA2∫0πsin2I+1θdθ

Use integral table for solving the expression.

=4Ï€A22.4.6...2l1.3.5...2l+1=4Ï€A22.4.6...2l21.2.3.5...2l2l+1=4Ï€A22ll22l+1!A=12I+1l!2l+1!Ï€

Thus, the normalization constant is12I+1l!2l+1!Ï€.12I+1l!2l+1!Ï€.

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Most popular questions from this chapter

(a) Construct the spatial wave function (ψ)for hydrogen in the state n=3,I=2,m=1.Express your answer as a function of r,θ,ϕ,anda(the Bohr radius) only—no other variables (p,z,etc.) or functions (p,v,etc.), or constants (A,c0,etc.), or derivatives, allowed (π is okay, and e, and 2, etc.).

(b) Check that this wave function is properly normalized, by carrying out the appropriate integrals over, θ,andϕ.

(c) Find the expectation value of rsin this state. For what range of s (positive and negative) is the result finite?

(a) Work out the Clebsch-Gordan coefficients for the case s1=1/2,s2=anything. Hint: You're looking for the coefficients A and Bin

|sm⟩=A|1212⟩|s2(m-12)⟩+B|12(-12)⟩|s2(m+12)⟩

such that|sm⟩ is an eigenstate of . Use the method of Equations 4.179 through 4.182. If you can't figure out whatSx(2) (for instance) does to|s2m2⟩ , refer back to Equation 4.136 and the line before Equation 4.147. Answer:

;role="math" localid="1658209512756" A=s2+12±m2s2+1;B=±s2+12±m2s2+1

where, the signs are determined bys=s2±1/2 .

(b) Check this general result against three or four entries in Table 4.8.

Show thatΘ=AIn[tan(θ2)]satisfies the θequation (Equation 4.25), for l = m = 0. This is the unacceptable "second solution" -- whats wrong with it?

An electron is in the spin state

χ=A3i4

(a) Determine the normalization constant .

(b) Find the expectation values of Sx,Sy , and Sz.

(c) Find the "uncertainties" ,σSx , σSyandσSz . (Note: These sigmas are standard deviations, not Pauli matrices!)

(d) Confirm that your results are consistent with all three uncertainty principles (Equation 4.100 and its cyclic permutations - only with in place ofL, of course).

(a) Prove that for a particle in a potential V(r)the rate of change of the expectation value of the orbital angular momentum L is equal to the expectation value of the torque:

ddt<L>=<N>

Where,

N=r×(VV)

(This is the rotational analog to Ehrenfest's theorem.)

(b) Show that d<L>/dt=0for any spherically symmetric potential. (This is one form of the quantum statement of conservation of angular momentum.)

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