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The raising and lowering operators change the value of m by one unit:

L±flm=(Alm)flm+1, (4.120).

Where Almare constant. Question: What is Alm, if the Eigen functions are to be normalized? Hint: First show thatL±is the Hermitian conjugate of L±(Since LxandLyare observables, you may assume they are Hermitian…but prove it if you like); then use Equation 4.112.

Short Answer

Expert verified

If the Eigen functions are to be normalized, they are upper and lower signs.

Step by step solution

01

Given.

The raising and lowering operators are:

L+flm=(Alm)flm+1,L-flm=(Blm)flm-1,

02

Eigen functions to be normalized

We start solving the problem by taking the inner product between a hydro genic set acted upon L±and L∓as following:

Alm=ħl(l+1)-m(m+1)=ħl(l+1)-m(m+1),Blm=ħl(l+1)-m(m+1)=ħl(l+1)-m(m+1),L2=L±L∓+Lz2±ħ³¢z(4.112).

Note what happens at the top and bottom of the ladder (i.e. when you apply L+L+tofllorL-tofl-lNow,usingEq.4.112,inthefromL±L∓=L2-Lz2∓ħ³¢zLL2=L±L∓+Lz2∓ħ³¢zL2=L4.112.

flmlLmL±flm=flmlL2-Lz2mhLzflm=flml[h2ll+l-h2m2mh2m]flm=h2ll+1-mm±1flmlflm=h2ll+1-mm±1=L±flmlL±flmUppersigns:ħ2ll+1-mm+1=L+flmlL+flm=Almflm+1lAlmflm+1=Alm2⇒Alm=ħll+1-mm+1Lowersigns:ħ2ll+1-mM-1=L-flmlL-flm=Blmflm-1lBlmflm-1=Blm2

At the top of the ladderm=lwe get All=0wegetAll=0, so there is no higher rung; at the bottom of the ladder m=l we getBl-l=0 , so there is no lower rung.

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Most popular questions from this chapter

(a) Find〈r〉and〈r²〉for an electron in the ground state of hydrogen. Express your answers in terms of the Bohr radius.

(b) Find〈x〉and (x2)for an electron in the ground state of hydrogen.

Hint: This requires no new integration—note that r2=x2+y2+z2,and exploit the symmetry of the ground state.

(c) Find〈x²〉in the state n=2,l=1,m=1. Hint: this state is not symmetrical in x, y, z. Usex=rsinθcosπx=rsinθcosϕ

(a) Find the eigenvalues and eigenspinors of Sy .

(b) If you measured Syon a particle in the general state X(Equation 4.139), what values might you get, and what is the probability of each? Check that the probabilities add up to 1 . Note: a and b need not be real!

(c) If you measuredSy2 , what values might you get, and with what probabilities?

What is the most probable value of r, in the ground state of hydrogen? (The answer is not zero!) Hint: First you must figure out the probability that the electron would be found between r and r + dr.

a) Check that the spin matrices (Equations 4.145 and 4.147) obey the fundamental commutation relations for angular momentum, Equation 4.134.

Sz=h2(100-1)(4.145).Sx=h2(0110),sy=h2(0-ii0)(4.147).[Sx,Sy]=ihSz,[Sy,Sz]=ihSx,[Sz,Sx]=ihSy(4.134).(b)ShowthatthePaulispinmatrices(Equation4.148)satisfytheproductruleσx≡(0110),σy≡(0-ii0),σz≡(100-1)(4.148).σjσk=δjk+i∑o'IjklσI,(4.153).

Wheretheindicesstandforx,y,orz,ando'jklistheLevi-Civitasymbol:+1ifjkl=123,231,or2=312;-1ifjkl=132,213,or321;otherwise.

Use equations 4.27 4.28 and 4.32 to construct Y00,Y21Check that they are normalized and orthogonal

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