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Suppose you could find a solution(r1,r2,...,rz)to the Schr枚dinger equation (Equation 5.25), for the Hamiltonian in Equation 5.24. Describe how you would construct from it a completely symmetric function, and a completely anti symmetric function, which also satisfy the Schr枚dinger equation, with the same energy.

role="math" localid="1658219144812" H^=j=1Z-22mj2-14o,0Ze2rj+1214o,0j1Ze2rj-rk (5.24).

role="math" localid="1658219153183" H^=E (5.25).

Short Answer

Expert verified

-=r1,r2,r3-r1,r2,r3-r1,r2,r3+r2,r3,r1-r3,r2,r1+r3,r1,r2-r1,r3,r2=0

Step by step solution

01

Definition of Schrodinger equation

The fundamental equation for characterizing quantum mechanical phenomena is the Schrodinger equation. It is a partial differential equation that illustrates how a physical system's wave function changes over time. The electron is a wave in the three-dimensional space surrounding the nucleus.

02

Finding a solution to Schrodinger equation

=Ar1,r2,r3,..rzr2,r1,r3,..,rz+r2,r3,r1,..,rz+etc.,

Where etc. runs over all permutations of the arguments,r1,r2,..,rz with a + sign for all even permutations (even number of transpositions rirjstarting from r1,r2,..,rzand 卤 for all odd permutations (+ for bosons, 鈥 for fermions).

At the end of the process, normalize the result to determine A. (Typically A=1/Z!, but this may not be right if the starting function is already symmetric under some interchanges.)

If 蠄 is symmetric in the first two arguments (or any other pair), the anti symmetric combination is zero.

For example, if Z = 3,

-=r1,r2,r3-r2,r1,r3+r2,r3,r1-r3,r1,r2+r3,r1,r2-r1,r3,r2=0

(They cancel in pairs).

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Most popular questions from this chapter

The density of copper is8.96g/cm3,and its atomic weight is63.5g/mole

(a) Calculate the Fermi energy for copper (Equation 5.43). Assume d = 1, and give your answer in electron volts.

EF=22m3蚁蟺22/3 (5.43).

(b) What is the corresponding electron velocity? Hint: SetEF=1/2mv2Is it safe to assume the electrons in copper are nonrelativistic?

(c) At what temperature would the characteristic thermal energyrole="math" localid="1656065555994" (kBT,wherekBkBis the Boltzmann constant and T is the Kelvin temperature) equal the Fermi energy, for copper? Comment: This is called the Fermi temperature,TF

. As long as the actual temperature is substantially below the Fermi temperature, the material can be regarded as 鈥渃old,鈥 with most of the electrons in the lowest accessible state. Since the melting point of copper is 1356 K, solid copper is always cold.

(d) Calculate the degeneracy pressure (Equation 5.46) of copper, in the electron gas model.

P=23EtotV=232kF5102m=322/325m5/3

(a) Write down the Hamiltonian for two noninteracting identical particles in the infinite square well. Verify that the fermion ground state given in Example 5.1 is an eigenfunction of H, with the appropriate eigenvalue.

(b) Find the next two excited states (beyond the ones in Example 5.1) - wave functions and energies - for each of the three cases (distinguishable, identical bosons, identical fermions).

(a) Using Equations 5.59 and 5.63, show that the wave function for a particle in the periodic delta-function potential can be written in the form

(X)=C[sinkx+e-ikasina-x]0xa

(b) There is an exception; At the top of a band where z is an integer multiple ofyiels(x)=0 yields .

Find the correct wave function for the case. Note what happens toeach delta function.

(a) Suppose you put both electrons in a helium atom into the n=2state;

what would the energy of the emitted electron be?

(b) Describe (quantitatively) the spectrum of the helium ion,He+.

(a)Use Equation5.113 to determine the energy density in the wavelength ranged. Hint: set()d蝇=-()诲位, and solve for()-

(b)Derive the Wien displacement law for the wavelength at which the blackbody energy density is a maximum
max=2.9010-3mKT

You'll need to solve the transcendental equation(5x)=5e-x, using a calculator (or a computer); get the numerical answer accurate to three significant digits.

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