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Suppose you had three particles, one in statea(x), one in stateb(x), and one in statec(x). Assuming a,b, andc are orthonormal, construct the three-particle states (analogous to Equations 5.15,5.16, and 5.17) representing

(a) distinguishable particles,

(b) identical bosons, and

(c) identical fermions.

Keep in mind that (b) must be completely symmetric, under interchange of any pair of particles, and (c) must be completely antisymmetric, in the same sense. Comment: There's a cute trick for constructing completely antisymmetric wave functions: Form the Slater determinant, whose first row isa(x1),b(x1),c(x1) , etc., whese second row isa(x2),b(x2),c(x2) , etc., and so on (this device works for any number of particles).

Short Answer

Expert verified

a) The distinguishable particles: x1,x2,x3颈蝉蠄ax1bx2cx3

b) The identical bosons

1,2,3,-16ax1bx2cx3+ax1bx2cx3+ax1bx2cx3+16ax1bx2cx3+ax1bx2cx3+ax1bx2cx3

c) The identical fermions

1,2,3,-16ax1bx2cx3+ax1bx2cx3+ax1bx2cx3+16ax1bx2cx3+ax1bx2cx3+ax1bx2cx3

Step by step solution

01

Definition of identical bosons ,identical ferminos and slater determinant

  • "Particles come in two types: the particles that make up matter, known as 'fermions,' and the particles that transport forces, known as 'bosons,' according to Carroll.
  • Fermions take up space, whereas bosons can be stacked on top of one another.
  • A Slater determinant is a formula in quantum mechanics that describes the wave function of a multi-fermionic system.
  • It satisfies anti-symmetry criteria, and thus the Pauli principle, by changing sign when two electrons are exchanged (or other fermions)

02

Determine the Slater determinant

WhenNfermionsarepresent,thewholewavefunctioncanberepresentedas:x2,...,xN)=1N!ax1bx1...Nx1ax1bx1...Nx2...axNbxN...NxNTheSlaterdeterminantisthenameforthisformula.

03

Determine the distinguishable particles

(a)

The total wave function for identifiable particles is simply the combination of three wave functions:

x1,x2,x3=ax1bx2cx3

04

Determine the  identical bosons

(b)

When we permute any two particles, the entire wave function for identical bosons must be symmetric:

x1,x2,x3,-16ax1bx2cx3+ax1bx2cx3+ax1bx2cx3+16ax1bx2cx3+ax1bx2cx3+ax1bx2cx3

05

Determine the  identical fermions

(c)

When we permute any two fermions, the whole wave function must be antisymmetric for identical fermions:

x1,x2,x3,-16ax1bx2cx3+ax1bx2cx3+ax1bx2cx3+16ax1bx2cx3+ax1bx2cx3+ax1bx2cx3

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Most popular questions from this chapter

(a) Figure out the electron configurations (in the notation of Equation

5.33) for the first two rows of the Periodic Table (up to neon), and check your

results against Table 5.1.

1s22s22p2(5.33).

(b) Figure out the corresponding total angular momenta, in the notation of

Equation 5.34, for the first four elements. List all the possibilities for boron,

carbon, and nitrogen.

LJ2S+1 (5.34).

(a) If aandb are orthogonal, and both normalized, what is the constant A in Equation 5.10?

(b) Ifrole="math" localid="1658225858808" a=b (and it is normalized), what is A ? (This case, of course, occurs only for bosons.)

a) Hund鈥檚 first rule says that, consistent with the Pauli principle, the state with the highest total spin (S) will have the lowest energy. What would this predict in the case of the excited states of helium?

(b) Hund鈥檚 second rule says that, for a given spin, the state with the highest total orbital angular momentum (L) , consistent with overall antisymmetrization, will have the lowest energy. Why doesn鈥檛 carbon haveL=2? Note that the 鈥渢op of the ladder鈥(ML=L)is symmetric.

(c) Hund鈥檚 third rule says that if a subshell(n,l)is no more than half filled,
then the lowest energy level hasJ=lL-SI; if it is more than half filled, thenJ=L+Shas the lowest energy. Use this to resolve the boron ambiguity inProblem 5.12(b).

(d) Use Hund鈥檚 rules, together with the fact that a symmetric spin state must go with an antisymmetric position state (and vice versa) to resolve the carbon and nitrogen ambiguities in Problem 5.12(b). Hint: Always go to the 鈥渢op of the ladder鈥 to figure out the symmetry of a state.

Discuss (qualitatively) the energy level scheme for helium if (a) electrons were identical bosons, and (b) if electrons were distinguishable particles (but with the same mass and charge). Pretend these 鈥渆lectrons鈥 still have spin 1/2, so the spin configurations are the singlet and the triplet.

(a) Suppose you put both electrons in a helium atom into the n=2state;

what would the energy of the emitted electron be?

(b) Describe (quantitatively) the spectrum of the helium ion,He+.

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