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Suppose you had three particles, one in statea(x), one in stateb(x), and one in statec(x). Assuming a,b, andc are orthonormal, construct the three-particle states (analogous to Equations 5.15,5.16, and 5.17) representing

(a) distinguishable particles,

(b) identical bosons, and

(c) identical fermions.

Keep in mind that (b) must be completely symmetric, under interchange of any pair of particles, and (c) must be completely antisymmetric, in the same sense. Comment: There's a cute trick for constructing completely antisymmetric wave functions: Form the Slater determinant, whose first row isa(x1),b(x1),c(x1) , etc., whese second row isa(x2),b(x2),c(x2) , etc., and so on (this device works for any number of particles).

Short Answer

Expert verified

a) The distinguishable particles: x1,x2,x3颈蝉蠄ax1bx2cx3

b) The identical bosons

1,2,3,-16ax1bx2cx3+ax1bx2cx3+ax1bx2cx3+16ax1bx2cx3+ax1bx2cx3+ax1bx2cx3

c) The identical fermions

1,2,3,-16ax1bx2cx3+ax1bx2cx3+ax1bx2cx3+16ax1bx2cx3+ax1bx2cx3+ax1bx2cx3

Step by step solution

01

Definition of identical bosons ,identical ferminos and slater determinant

  • "Particles come in two types: the particles that make up matter, known as 'fermions,' and the particles that transport forces, known as 'bosons,' according to Carroll.
  • Fermions take up space, whereas bosons can be stacked on top of one another.
  • A Slater determinant is a formula in quantum mechanics that describes the wave function of a multi-fermionic system.
  • It satisfies anti-symmetry criteria, and thus the Pauli principle, by changing sign when two electrons are exchanged (or other fermions)

02

Determine the Slater determinant

WhenNfermionsarepresent,thewholewavefunctioncanberepresentedas:x2,...,xN)=1N!ax1bx1...Nx1ax1bx1...Nx2...axNbxN...NxNTheSlaterdeterminantisthenameforthisformula.

03

Determine the distinguishable particles

(a)

The total wave function for identifiable particles is simply the combination of three wave functions:

x1,x2,x3=ax1bx2cx3

04

Determine the  identical bosons

(b)

When we permute any two particles, the entire wave function for identical bosons must be symmetric:

x1,x2,x3,-16ax1bx2cx3+ax1bx2cx3+ax1bx2cx3+16ax1bx2cx3+ax1bx2cx3+ax1bx2cx3

05

Determine the  identical fermions

(c)

When we permute any two fermions, the whole wave function must be antisymmetric for identical fermions:

x1,x2,x3,-16ax1bx2cx3+ax1bx2cx3+ax1bx2cx3+16ax1bx2cx3+ax1bx2cx3+ax1bx2cx3

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Most popular questions from this chapter

(a) Calculate<1/r1-r2>for the state0(Equation 5.30). Hint: Dod3r2integral

first, using spherical coordinates, and setting the polar axis alongr1, so

that

0r1,r2=100r1100r2=8蟺补3e-2r1+r2/a(5.30).

r1-r2=r12+r22-2r1r2肠辞蝉胃2.

The2integral is easy, but be careful to take the positive root. You鈥檒l have to

break ther2integral into two pieces, one ranging from 0 tor1,the other fromr1to

Answer: 5/4a.

(b) Use your result in (a) to estimate the electron interaction energy in the ground state of helium. Express your answer in electron volts, and add it toE0(Equation 5.31) to get a corrected estimate of the ground state energy. Compare the experimental value. (Of course, we鈥檙e still working with an approximate wave function, so don鈥檛 expect perfect agreement.)

E0=8-13.6eV=-109eV(5.31).

(a) Find the percent error in Stirling鈥檚 approximation for z = 10 ?

(b)What is the smallest integer z such that the error is less than 1%?

The density of copper is8.96g/cm3,and its atomic weight is63.5g/mole

(a) Calculate the Fermi energy for copper (Equation 5.43). Assume d = 1, and give your answer in electron volts.

EF=22m3蚁蟺22/3 (5.43).

(b) What is the corresponding electron velocity? Hint: SetEF=1/2mv2Is it safe to assume the electrons in copper are nonrelativistic?

(c) At what temperature would the characteristic thermal energyrole="math" localid="1656065555994" (kBT,wherekBkBis the Boltzmann constant and T is the Kelvin temperature) equal the Fermi energy, for copper? Comment: This is called the Fermi temperature,TF

. As long as the actual temperature is substantially below the Fermi temperature, the material can be regarded as 鈥渃old,鈥 with most of the electrons in the lowest accessible state. Since the melting point of copper is 1356 K, solid copper is always cold.

(d) Calculate the degeneracy pressure (Equation 5.46) of copper, in the electron gas model.

P=23EtotV=232kF5102m=322/325m5/3

a) Hund鈥檚 first rule says that, consistent with the Pauli principle, the state with the highest total spin (S) will have the lowest energy. What would this predict in the case of the excited states of helium?

(b) Hund鈥檚 second rule says that, for a given spin, the state with the highest total orbital angular momentum (L) , consistent with overall antisymmetrization, will have the lowest energy. Why doesn鈥檛 carbon haveL=2? Note that the 鈥渢op of the ladder鈥(ML=L)is symmetric.

(c) Hund鈥檚 third rule says that if a subshell(n,l)is no more than half filled,
then the lowest energy level hasJ=lL-SI; if it is more than half filled, thenJ=L+Shas the lowest energy. Use this to resolve the boron ambiguity inProblem 5.12(b).

(d) Use Hund鈥檚 rules, together with the fact that a symmetric spin state must go with an antisymmetric position state (and vice versa) to resolve the carbon and nitrogen ambiguities in Problem 5.12(b). Hint: Always go to the 鈥渢op of the ladder鈥 to figure out the symmetry of a state.

Find the average energy per free electron (Etot/Nd), as a fraction of the

Fermi energy. Answer:(3/5)EF

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