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The temperature of 2.00molof an ideal monoatomic gas is raised 15.0Kat constant volume. What are

  1. The work Wdone by the gas
  2. The energy transferred as heat Q
  3. The changeΔEintin the internal energy of the gas
  4. The changeΔKin average kinetic energy per atom?

Short Answer

Expert verified
  1. The work done by the gas is zero.
  2. The energy transferred as heat Q is 374J.
  3. The change ΔEintin the internal energy of the gas is 374J.
  4. The change ΔKin the average kinetic energy per atom is 3.11×10-22J.

Step by step solution

01

Given

  • Number of moles of an ideal monoatomic gas,n=2.00
  • Temperature difference,ΔT=15.0K
  • Change in volume,ΔV=0
02

Understanding the concept

The expression for the amount of energy transferred to the gas is given by,

Q=nCPΔT

Here Q is the amount of energy transferred to gas, n is the number of moles, CP is the specific heat capacity at constant volume andΔTis the temperature difference.

The expression for the work done by the gas is given by,

W=pΔV

Here W is the work done by the gas, p is the pressure and ΔVis the change in the volume.

03

(a) Calculate the work W done by the gas

Work done by the gas is;

W=pΔV

But,

ΔV=0

Hence,

W=0

Therefore, the work W done by the gas is zero.

04

(b) Calculate the energy transferred as heat Q

Heat energy is given by

Q=nCvΔTQ=nCvΔT

But, for a monoatomic gas,

Cv=32R

Substitute role="math" localid="1662468781681" 32Rfor CV into the above equation,

Q=n32RΔT
role="math" localid="1662469017230" =2328.31415.0=374.13=374J

Therefore, the energy transferred as heat Q is 374J.

05

(c) Calculate the change in the internal energy of the gas

According to the first law of thermodynamics,

ΔEint=Q-W

Substitute 374J for Q and 0J for W into the above equation,

role="math" localid="1662469480888" ΔEint=374-0=374J

Therefore, the change ΔEintin the internal energy of the gas is 374J.

06

(d) Calculate the change in average kinetic energy per atom

No. of atoms (N) = No. of moles x Avogadro no.

N=2×6.02×1023=12.04×1023

Changeintheaveragekineticenergyperatom(ΔK)=(ΔEint)N

Substitute 374J forΔEintand 12.04×1023for into the above equation,

role="math" localid="1662470169132" K=37412.04×1023=31.063×10-23=3.11×10-22

Therefore, the change in the average kinetic energy per atom is3.11×10-22J

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