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91Ó°ÊÓ

An ideal gas initially at300 Kis compressed at a constant pressure of25 N/m2from a volume of3.0 m3to a volume of1.8m3. In the process,75 Jis lost by the gas as heat. What are

(a) the change in internal energy of the gas and

(b) the final temperature of the gas?

Short Answer

Expert verified
  1. The internal energy change in the gas isΔEint=−45J .
  2. The temperature of the gas changes to180‿é .

Step by step solution

01

Concept

The process that takes place at constant pressure is called an isobaric process. Using the formulas for work done W in an isobaric process, and the first law of thermodynamics, we can find the change in the internal energyΔ·¡intof the gas. Also, by using theideal gas law in the ratio form, we can find the final temperature T2of the gas.

1.The work done W in anisobaric process is

W=±èΔ³Õ

2.The ideal gas law in ratio form is

T2=T1V2V1

3.Thechange in the internal energy is

Δ·¡int=Q-W

02

Step 2: Given Data

  1. The pressure.p=25 N/³¾2
  2. The final volumeVf=1.8m3
  3. The initial volume.Vi=3.0m3
  4. The initial temperatureT1=300K
  5. In the process, the energy lost by the gas as heat isQ=−75J .
03

Step 3: Calculations

a.The work done in anisobaricprocess is expressed as-

W=pΔV

Where p is the pressure and ΔV=(Vf−Vi)is change in the volume

Therefore,

W=p(Vf−Vi)=25 N/m2×(1.8″¾3−3.0″¾3)=−30 J

From the first law of thermodynamics, we have-

ΔEint=Q−W

Where Q is the heat transferred andΔEintis the change in the internal energy o the gas. It is given that Q amount of energy leaves the system; therefore, we can consider Q as negative.Q=−75 J

ΔEint=−75 J−(−30 J)=−75 J+(30 J)=−45 J

Internal energy is decreased by−45 J

b.Since the pressure is constant and the number of moles presumed are constant, the ideal gas law can be written as-

T2=T1(V2V1)=300K×(1.8 m33.0 m3)=180‿é

04

Conclusion

The change in internal energy of the gas is -45Jand the final temperature of the gas is 180‿é.

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Most popular questions from this chapter

During a compression at a constant pressure of 250 P²¹, the volume of an ideal gas decreases from 0.80″¾3to0.20″¾3 . The initial temperature is 360‿é, and the gas loses 210 Jas heat.

  1. What is the change in internal energy of gas?
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The dot in Figre 19-18bpresents the initial state of a gas, and the isotherm through the dot divides the p-V diagram into regions 1 and 2. For the following processes, determine whether the change Δ·¡intin the internal energy of the gas is positive, negative, or zero: (a) the gas moves up along the isotherm, (b) it moves down along the isotherm, (c) it moves to anywhere in region, and (d) it moves to anywhere in region.

(a) What is the number of molecules per cubic meter in air at20 °Cand at a pressure of1.0 atm(=1.01×105 Pa)?

(b) What is the mass of1.0 m3of this air? Assume that 75% of the molecules are nitrogen (N2) and 25% are oxygen (O2).

In a certain particle accelerator, protons travel around a circular path of diameter 23.0 min an evacuated chamber, whose residual gas is at295 Kand1.00×10-6torrpressure.

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