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A gas within a closed chamber undergoes the cycle shown in the p-V diagram of Figure. The horizontal scale is set byVs=4.0m3. Calculate the net energy added to the system as heat during one complete cycle.

Short Answer

Expert verified

The net energy added to the system as heat during one complete cycle is−30 J

Step by step solution

01

Identification of given data

From thegiven figure, we have the volume as

i)VA=Vc=1″¾3

ii)VB=4″¾3

And pressure as

iii)pB=pC=30 P²¹

iv)pA=10 P²¹

02

Significance of work done in terms pressure and change in volume

We have the integral W=∫p.dV

i.For an isochoric process, pressurepis constant; then,W=pΔV

ii. For an isochoric process,is constant; therefore, we getW=0.

The internal energy is the same over the entire cycle, so the heat energy absorbed must be equal to the work done:

W=Q.

Over the path Ato Bthe pressure is a linear function of volume, so we write.

p=a+bV

Then the work done

role="math" localid="1661839902618" WAB=∫VAVBpdV

During BC cycle, pressure is constant. Then,WBC=pBΔVBC

During the CA cycle, volume is constant, so no work is done during the process, soWCA=0

Formulae:

The work done by the heat system during the path from A to reach B,

WAB=VAVBpdV …(¾±)

The total work done, W=WAB+WBC+WCA …(¾±¾±)

The work done when pressure is constant, W=pΔV …(¾±¾±¾±)

03

Determining the net work done

Over the path. AtoBthe pressure is a linear function of volume, so we write the pressure expression as:

p=a+bV …(¾±±¹)

Then, the work done using equation (i) is given as:

.WAB=VAVB(a+bV)dV

WAB=a(VB−VA)+12b(VB2−VA2) …(±¹)

First, we have to find the values ofa a²Ô»å b. From the figurep=10 P²¹whenv=1.0″¾3,and.p=30 P²¹whenv=4.0″¾3 Thus, we have equation (iv) as

Then, solving these two equations, we have

a=103 P²¹andb=203 P²¹/m3.

Substituting these values and the given values, we get the form of equation (a) as:

WAB=(103Pa)(4.0″¾3−1.0″¾3)+12(203 P²¹/m3)[(4.0″¾3)2−(1.0″¾3)2]=10 J+1503 J=60 J

During BC cycle, pressure is constant; then work done using equation (iii) is given as:

WBC=pB(VC−VB)=30 P²¹(1.0″¾3−4.0″¾3)=−90 J

During the CA cycle, volume is constant, so no work is done during the process, so

WCA=0

The total work done using equation (ii) is given as:

W=60 J−90 J+0=−30 J

Thus, the total heat absorbed isQ=W=−30 J

Thus, this means that the gas loses of30 J energy in the form of heat.

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