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A 150 gcopper bowl contains 220 gof water, both at20.0∘C. A very hot 300 gcopper cylinder is dropped into the water, causing the water to boil, with 5.00 g being converted to steam. The final temperature of the system is100∘C. Neglect energy transfers with the environment. (a) How much energy (in calories) is transferred to the water as heat? (b) How much to the bowl? (c) What is the original temperature of the cylinder?

Short Answer

Expert verified
  1. Amount of energy transferred to the environment is 20.3 kcal
  2. Amount of energy transferred to the bowl is 1.11 kcal
  3. The original temperature of the cylinder is 873∘C.

Step by step solution

01

Identification of given data

  1. Mass of copperMC=150g
  2. Mass of waterMW=220g
  3. Initial temperature of copper and water isTi=20∘C
  4. Final temperature of the system isTf=100∘C
  5. Mass that is converted to steam isMs=5.00g
  6. Latent heat of vaporization isLv=539cal/g
02

Significance of specific heat

Specific heat is the amount of heat required to raise the temperature of a unit mass of a substance by one degree. We can find the amount of heat energy required to raise the temperature of water to its boiling point and the amount of heat required to convert some part of the water to steam. Using this heat, we can calculate the temperature of the cylinder as well. We have to use the equation for specific heat and latent heat of vaporization to solve this.

Formula:

The total heat energy required to raise the temperature,Q=MWCW∆T+LVMS …(¾±)

Here, Q is heat energy, MW is mass of water, CW is specific heat capacity of water,∆Tis change in temperature, LV is latent heat of vaporization, MS and is mass of steam.

The initial temperature of a heat body,Ti=Qw+QbCcMc+Tf …(¾±¾±)

Here, Ti is initial temperature, QW is heat required to change the temperature, Qb heat transferred to the bowl.

03

(a) Determining the total energy transferred to the environment

The total amount of heat required raising the temperature of water and also to convert the water to vapor can be given using equation (i) and the given values as follows:

QW=220g×1calg∘C100-20∘C+539cal/g×5.00g=220g×80∘C+2695cal=20295cal≈20.3kcal

Hence, the amount of total energy transferred to the environment is 20.3 kcal

04

b) Determining the heat transferred to the bowl

Using equation (i) and the given values, the heat transferred to the bowl is given as:

Qb=0.0923cal/g.C∘×150g×100oC-20oC=1107.6cal≈1.11kcal

Hence, the total amount of energy transferred to the bowl is 1.11 kcal

05

(c) Determining the original temperature of the cylinder

Let, the original temperature of the cylinder isTi. So, this temperature value can be given using equation (ii) as follows:

Ti=20.3×103cal+1.11×103cal0.0923cal/goC×300g+100oC=21.4127.69+100=873oC

Hence, the original temperature is873oC.

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