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The isotope K40can decay to either C40aor A40r; assume both decays have a half-life of 1.26×109y. The ratio of the Caproduced to Ar theproduced is 8.54/1 = 8.54. A sample originally had onlyK40. It now has equal amounts ofK40andA40r; that is, the ratio of Kto Aris 1/1 = 1. How old is the sample? (Hint:Work this like other radioactive-dating problems, except that this decay has two products.)

Short Answer

Expert verified

The sample is4.24×109y old.

Step by step solution

01

Given data

Half-life of 40Caand 40Ar,T1/2=1.26×109y

Ratio of Ca to Ar isNca/Nk=8.54/1.

Ratio of K to Ar is NAr/Nk=1.

02

Understanding the concept of radioactive dating

The concept of radioactive dating is used to know the age of the fossil using the given decay rates. Here, the problem is of a parent nucleus that can decay into two products. Being the products of the decay, the number of atoms of calcium and argon were initially potassium atoms before the decay. Thus, the total number of initial potassium atoms can be given as the sum of all the three atoms present in the rock after the decay at the given time.

Formulae:

The disintegration constant, λ=ln2T1/2…....(1)

where, T1/2is the half-life of the substance.

The undecayed sample remaining after a given time, N=N0e-λt............(2)

03

Calculation of the age of the sample

We note that every calcium-40 atom and krypton-40 atom found now in the sample was once one of the original numbers of potassium atoms.

Thus, the total number of initial potassium-40 atoms can be given as:

Nko=Nk+NAr+Nca

Thus, substituting equation (1) in (2) with the above data, we can get the age of the sample as follows:

lnNkNko=-ln2T1/2tlnNkNk+NAr+Nca=-ln21.26×109ytln11+1+8.54=-0.55501×10-9/ytln110.54=0.55501×10-9/ytt=2.35520.55501×10-9/yt=4.24×109y

Hence, the age of the sample is 4.24×109y.

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