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(a) For a given value of the principal quantum number nfor a hydrogen atom, how many values of the orbital quantum number Iare possible?

(b) For a given value of I, how many values of the orbital magnetic quantum numbermIare possible?

(c) For a given value of n, how many values ofmIare possible?

Short Answer

Expert verified

(a) There are distinct values of orbital quantum number I are possible For a given value of the principal quantum number for a hydrogen atom.

(b) There are 2I + 1 distinct values of orbital magnetic quantum number mIfor a given value of .

(c) There are 2n + 1 distinct values of orbital magnetic quantum number mIfor a given value of n .

Step by step solution

01

Principal, orbital, and orbital magnetic quantum number:

Each atom's electron is given one of four quantum numbers, the primary quantum number n , to describe the state of that electron.

A measurement of the angular momentum's magnitude is the orbital quantum number I .

The angular momentum vector's orientation in space is connected to the orbital magnetic quantum numbermI .

02

(a) Finding how many values of the orbital quantum number  are possible for a given value of the principal quantum number  for a hydrogen atom:

For a hydrogen atom, the values of orbital quantum number I for a given value of n are 0,1,2,....,(n-1) .

Hence, there are distinct values of orbital quantum number I are possible For a given value of the principal quantum number n for a hydrogen atom.

03

(b) Finding how many value the orbital magnetic quantum number mI are possible for a given value of I :

For a hydrogen atom, the values of orbital magnetic quantum number for a given value of I is -I,-(I-1),-(I-2),............,+(I-1),+I.

Hence, there are 2I+1 distinct values of orbital magnetic quantum number mIfor a given value of I .

04

(c) Finding how many value the orbital magnetic quantum number  are possible for a given value of

In step 3, there are 2I+1 distinct values of orbital magnetic quantum number mIfor a given value of I .

Also, in step 2, there are n distinct values of orbital quantum number I are possible For a given value of the principal quantum number for a hydrogen atom.

The conclusion is that, there are 2n+1 distinct values of orbital magnetic quantum number mI for a given value of n .

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