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The two-dimensional, infinite corral of Fig. 39-31 is square, with edge length L = 150 pm. A square probe is centered at xy coordinates (0.200L,0.800L)and has an x width of 5.00 pm and a y width of 5.00 pm . What is the probability of detection if the electron is in the E1.3energy state?

Short Answer

Expert verified

The required probability of detection is 1.4×10-3.

Step by step solution

01

Describe the wave functions for an electron in a two-dimensional well:

The wave functions for an electron in a two-dimensional well are given by,

ψnx,ny(x,y)=ψnx(x)ψny(y)=2Lxsin(nxπLxx)2Lysin(nyπLyy)

02

Find the probability of detection if the electron is in the   energy state:

In this case, the well is square, so Lx=Ly=L. Therefore,

ψnx,nyx,y=2LsinnxπLx2LsinnyπLy=2LsinnxπLxsinnyπLy

The probability of detection at x,yis given by,

px,y=ψnx,nyx,y2dxdy

Where, dx and dy are the width and height of the detection area, which are the width and height of the probe.

px,y=4L2sin2nxπLxsin2nyπLydxdy

It is given that the probe is placed at (x,y) = ( 0.200L, 0.800L ). Therefore,

px,y=4L2sin2nxπL0.200Lsin2nyπL0.800Ldxdy=4L2sin20.200nxπsin20.800nyπdxdy

Substitute 150pmforL,5.00pmfordx,5.00pmfordy,1bfornx,and3fornyin the above probability formula.

px,y=4150pm2sin20.200×1×πsin20.800×3×π5.00pm2=1.77×10-4pm-20.587820.951225.00pm2=1.77×10-4pm-20.010520.131225.00pm2=1.4×10-3

Therefore, the required probability of detection is 1.4×10-3.

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in which the subscripts on Ψ(r,θ) give the values of the quantum numbers n , l , and ml the angles θand ϕ are defined in Fig. 39-22. Note that the first wave function is real but the others, which involve the imaginary number i, are complex. Find the radial probability density P(r) for (a)Ψ210 and (b)Ψ21+1 (same as for Ψ21-1 ). (c) Show that each P(r) is consistent with the corresponding dot plot in Fig. 39-23. (d) Add the radial probability densities for Ψ210 , Ψ21+1 , andΨ21-1 and then show that the sum is spherically symmetric, depending only on r.

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