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Figureis a one-axis graph along which two of the allowed energy values (levels) of an atom are plotted. When the atom is placed in a magnetic field of 0.500TE2, the graph changes to that of Figure bbecause of the energy associated withorb.B. Level E1is unchanged, but level splits into a (closely spaced) triplet of levels. What are the allowed values ofm1associated with (a) Energy level E1and (b) Energy level E2? (c) In joules, what amount of energy is represented by the spacing between the triplet levels?

Short Answer

Expert verified

a) Allowed values ofml associated with energy levelE1 is zero.

b)Allowed values ofml associated with energy levelE2asupper line hasml=+1and lower will beml=-1

c) Amount of energy in joules represented by the spacing between the triplet levels is 4.6410-24J.

Step by step solution

01

Listing the given quantities

Magnetic field,Bext=0.500T

02

Understanding the concepts of magnetic dipole moment

To calculate the mlvalues, we can use the formula of energy associated with the orientation of an orbital magnetic dipole moment in an external field. Substituting the values of ml, Bohr magnetron, and the magnetic field, we can calculate the spacing between the energy levels.

Formula:

U=-mlBBext

03

(a) Calculations of the allowed values of ml associated with energy level E1

The energyU associated with the orientation of the orbital magnetic dipole moment in an external magnetic fieldBextis

U=-orb.Bext=-orb,zBext

Since

orb,z=-mleh4m

Also,

eh4m=B

Thus,

orb,z=-mlB

Therefore,

U=-orb.Bext=-mlBBext

From the figure, we can observe that there is no splitting of energy levelE1 in the external magnetic field.

Hence its energy does not change by the application of external magnetic fieldBext

HenceUml=0

ml=0

04

(b) Calculations of  allowed values of ml associated with energy level E2

The energy levelE2 splits into three energy levels, with the middle one unshifted from the original value of energy. E2Hence itsmlvalue is zero.

In other two lines, one line is shifted above the unshifted line and another one is shifted below.

Hence the upper line hasml=+1and lower will beml=-1

05

(c) Calculations ofamount of energy in joules represented by the spacing between the triplet levels

The spacing between the energy levels is given by

U=BBext=-mlBBext

For any pair of adjacent levels in triplet,

ml=1

Therefore,

where,B is Bohr magnetron, and its value isB=9.2710-24J/T

U=9.2710-24JT0.500T=4.6410-24J

Amount of energy in joules represented by the spacing between the triplet levels is 4.6410-24J.

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