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TheKα x-ray line for any element arises because of a transition between the Kshell (n=1) and the Lshell (n=2). Figure 40-13 shows this line (for a molybdenum target) occurring at a single wavelength. With higher resolution, however, the line splits into several wavelength components because the Lshell does not have a unique energy.

(a) How many components does the Kαline have?

(b) Similarly, how many components does the Kβline have?

Short Answer

Expert verified

a) The Kαline has 3.5×108components of a single wavelength.

b) The Kβline has 4.1×108components of a single wavelength.

Step by step solution

01

The given data

a) The Kαline arises because of the transition between the K-shell (n=1) and the L-shell (n=2) .

b) TheKβline arises because of the transition between the K-shell (n=1) and the M-shell (n=3) .

c) The target is molybdenum with atomic number (Z=42).

d) A single wavelength splits into several wavelengths.

02

Understanding the concept of wavenumber

A single wavelength splits into several wavelength components as spectral lines considering the transition from the K-shell to the L-shell or the transition from K-shell to the M-shell. Thus, using the Rydberg equation for wavenumber, we can get the number of components for each transition accordingly.

Formula:

The Rydberg formula for a wavenumber of a transition between two states,
v=RHZ1n12-1n22,WhereRH=1.097×107m-1 …â¶Ä¦..(¾±)

03

a) Calculation of the components for the Kα line

For a transition, the excitation takes place between statesn1=1 and n2=2.

Thus, the number of components of the wavelengths can be given using equation (i) as follows:

v=1.097×107m-142112-122=34.555×107m-1≈3.5×108m-1

Hence, the required value of components is3.5×108 for a single wavelength.

04

b) Calculation of the components for the Kβ line

For aKβ transition, the excitation takes place between statesn1=1 and n2=3.

Thus, the number of components of the wavelengths can be given using equation (i) as follows:

v=1.097×107m-142112-132=40.955×107m-1≈4.1×108m-1

Hence, the required value of components is4.1×108 for a single wavelength.

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