/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Q 5.69  What happens when you spread s... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

What happens when you spread salt crystals over an icy sidewalk? Why is this procedure rarely used in very cold climates?

Short Answer

Expert verified

The transition temperature between the phases will be lower than, implying that the ice on the street will not freeze until the temperature drops to the new phase temperature.

Step by step solution

01

Given information

Salt crystals are spread over an icy sidewalk.

02

Explanation

We know that water freezes at 0°C, thus sprinkling salt on the icy sidewalk will lower the phase temperature. As a result, the transition temperature between the phases will be lower than 0°C, implying that the ice on the street will not freeze until the temperature drops to the new phase temperature.

This approach will not work in very cold nations since the temperature is below the phase temperature of the water and salt mixture, and the mixture also causes concrete damage, so it is only used in very cold countries on rare occasions.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

The compression factor of a fluid is defined as the ratio PV/NkT; the deviation of this quantity from 1 is a measure of how much the fluid differs from an ideal gas. Calculate the compression factor of a Van der Waals fluid at the critical point, and note that the value is independent of a and b. (Experimental values of compression factors at the critical point are generally lower than the Van der Waals prediction, for instance, 0.227 for H22O, 0.274 for CO22, and 0.305 for He.)

Assume that the air you exhale is at 35°C, with a relative humidity of 90%. This air immediately mixes with environmental air at 5°C and unknown relative humidity; during the mixing, a variety of intermediate temperatures and water vapour percentages temporarily occur. If you are able to "see your breath" due to the formation of cloud droplets during this mixing, what can you conclude about the relative humidity of your environment? (Refer to the vapour pressure graph drawn in Problem 5.42.)

Use a Maxwell relation from the previous problem and the third law of thermodynamics to prove that the thermal expansion coefficient β(defined in Problem 1.7) must be zero at T=0.

Sulfuric acid, H2SO4,readily dissociates intoH+andHSO4-H+andHSO4-ions

H2SO4⟶H++HSO4-

The hydrogen sulfate ion, in turn, can dissociate again:

HSO4-⟷H++SO42-

The equilibrium constants for these reactions, in aqueous solutions at 298 K, are approximately 10 and 10*, respectively. (For dissociation of acids it is usually more convenient to look up K than ∆G°. By the way, the negative base-10 logarithm of K for such a reaction is called pK, in analogy to pH. So for the first reaction pK = -2, while for the second reaction pK = 1.9.)

(a) Argue that the first reaction tends so strongly to the right that we might as well consider it to have gone to completion, in any solution that could possibly be considered dilute. At what pH values would a significant fraction of the sulfuric acid not be dissociated?

(b) In industrialized regions where lots of coal is burned, the concentration of sulfate in rainwater is typically 5 x 10 mol/kg. The sulfate can take any of the chemical forms mentioned above. Show that, at this concentration, the second reaction will also have gone essentially to completion, so all the sulfate is in the form of SOg. What is the pH of this rainwater?

(c) Explain why you can neglect dissociation of water into H* and OH in answering the previous question. (d) At what pH would dissolved sulfate be equally distributed between HSO and SO2-?

Suppose you have a mole of water at 25°Cand atmospheric pressure. Use the data at the back of this book to determine what happens to its Gibbs free energy if you raise the temperature to30°C. To compensate for this change, you could increase the pressure on the water. How much pressure would be required?

See all solutions

Recommended explanations on Physics Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.