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Your 200 g cup of tea is boiling-hot. About how much ice should you add to bring it down to a comfortable sipping temperature of 65°C? (Assume that the ice is initially 65°C. The specific heat capacity of ice isrole="math" localid="1650146844935" 0.5cal/g°C.

Short Answer

Expert verified

Short Answer:

m=45.9g

Step by step solution

01

Given Information:

Mass of cup = 200 g

Initial Temp = 65 oC

02

Step 1:

We have a 200 gram cup of boiling tea that we'd want to chill down to 65°C before we drink it, by putting a mass m of ice (initially at -15 oC ) into the tea Given that the specific heat cal·g-1·K-1. Assume that the tea have the same heat capacity as pure water 1 cal·g-1·K-1, the tea must decrease by 35Kso it must give up an amount of heat:

Qneater=mcΔT

Qtea=200×1×(35)-7000cal

This heat goes into, first, heating the ice by 15 degrees to its melting point, then melting it, then heating the resulting water to 65 oC.

03

Step 2:

For the first step, the required heat raises the temperature of ice to its melting point is:

Q1=mcΔT

where m is the mass of the ice, c is the specific heat of ice 0.5cal·g-1·K-1, and∆T is the temperature difference between the initial temperature of ice and the melting point, so

role="math" localid="1650148419303" Q1=m×0.5×(0-(-15))=7.5mcal

In the second step, the amount of heat required to melt the ice is:

Q2=m·L

where L is the latent heat, and it's 80cal/gfor melting ice, so:

Q2=m·80=80mcal

- In the third step, the amount of heat lost by the tea to make the resulting water temperature at 65°Cis,

Q3=mcΔT

where m is the mass of the melted ice (water), c is the specific heat of water 1cal·g-1·K-1and ∆Tis the temperature difference between the initial temperature of melted ice and the final temperature of the mixture at 65°C, so:

Q3=m×1×(65-0)

=65 mcal

04

Step 3:

The sum of these three heats is equal to the heat lost by the tea is:

Qcas=Q1+Q2+Q3

=7.5mcal+80mcal+65mcal

=152.5mcal

Therefore:

m=45.9g

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Most popular questions from this chapter

A battery is connected in series to a resistor, which is immersed in water (to prepare a nice hot cup of tea). Would you classify the flow of energy from the battery to the resistor as "heat" or "work"? What about the flow of energy from the resistor to the water?

In analogy with the thermal conductivity, derive an approximate formula for the viscosity of an ideal gas in terms of its density, mean free path, and average thermal speed. Show explicitly that the viscosity is independent of pressure and proportional to the square root of the temperature. Evaluate your formula numerically for air at room temperature and compare to the experimental value quoted in the text.

Measured heat capacities of solids and liquids are almost always at constant pressure, not constant volume. To see why, estimate the pressure needed to keep Vfixed as Tincreases, as follows.

(a) First imagine slightly increasing the temperature of a material at constant pressure. Write the change in volume,dV1, in terms of dTand the thermal expansion coefficient βintroduced in Problem 1.7.

(b) Now imagine slightly compressing the material, holding its temperature fixed. Write the change in volume for this process, dV2, in terms of dPand the isothermal compressibility κT, defined as

κT≡−1V∂V∂PT

(c) Finally, imagine that you compress the material just enough in part (b) to offset the expansion in part (a). Then the ratio of dPtodTis equal to (∂P/∂T)V, since there is no net change in volume. Express this partial derivative in terms of βandκT. Then express it more abstractly in terms of the partial derivatives used to define βandκT. For the second expression you should obtain

∂P∂TV=−(∂V/∂T)P(∂V/∂P)T

This result is actually a purely mathematical relation, true for any three quantities that are related in such a way that any two determine the third.

(d) Compute β,κT,and(∂P/∂T)Vfor an ideal gas, and check that the three expressions satisfy the identity you found in part (c).

(e) For water at 25∘C,β=2.57×10−4K−1andκT=4.52×10−10Pa−1. Suppose you increase the temperature of some water from 20∘Cto30∘C. How much pressure must you apply to prevent it from expanding? Repeat the calculation for mercury, for which (at25∘C)β=1.81×10−4K−1andκT=4.04×10−11Pa−1

Given the choice, would you rather measure the heat capacities of these substances at constant vor at constant p?

In a Diesel engine, atmospheric air is quickly compressed to about 1/20 of its original volume. Estimate the temperature of the air after compression, and explain why a Diesel engine does not require spark plugs.

Problem 1.49. Consider the combustion of one mole of H2with1/2 mole ofO2 under standard conditions, as discussed in the text. How much of the heat energy produced comes from a decrease in the internal energy of the system, and how much comes from work done by the collapsing atmosphere? (Treat the volume of the liquid water as negligible.)

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