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Imagine a world in which space is two-dimensional, but the laws of physics are otherwise the same. Derive the speed distribution formula for an ideal gas of nonrelativistic particles in this fictitious world, and sketch this distribution. Carefully explain the similarities and differences between the two-dimensional and three-dimensional cases. What is the most likely velocity vector? What is the most likely speed?

Short Answer

Expert verified

The probability of is, Pv=m2蟺办罢2蟺惫别-mv22kT

The most likely velocity and speed is, vmax=kTm

Step by step solution

01

Given information 

We need to find out the probability and most likely velocity for a world in which space is two-dimensional, but the laws of physics are otherwise the same.

02

Explanation

The probability of a molecule in 2D plane is proportional to Boltzmann factor e-mv22kT, in 2D plane the velocity life is inside the circle of radius v, which means that the no. of the velocity vectors is proportional to the circumference of this circle, i.e. 2蟺惫, so we can give the probability as

role="math" localid="1650192711584" P(v)2蟺惫别-mv22kT

P(v)=C2蟺惫别-mv22kT Let it be equation 1

Where C is constant

To find this constant we use the fact that the integration of the probability all over space is unity,

So,

0P(v)-C20ve-mv22kT-1

But,

xe-ax2=-e-ax22a

Here, we have a=m2kT

So,

C2kTme-mv22kT0=1C2kTm0-1=1C2kTm=1C=m2蟺办罢

Now, substitute above value of C in (1) to get,

Pv=m2蟺办罢2蟺惫别-mv22kT

03

Clarification   

As in 3D plane the probability fall exponentially e-v2as v.However, at low velocities the linear term dominate, so instead of the parabolic we have linear, plot the probability we set:

v'=vmkT

In terms of v'the probability can be given as,

Pv=mkTv'e-v'22

So, we plot a graph between P(v)and v', were the slope of the linear part of the graph is,

Slope= mkT

04

Simplify

To find the most likely speed, we take the derivative of the probability then set it equals to zero,

dPdv=0ddvve-av2=0

Here, a=m2kT

So,

-2av2e-av2+e-av2=02av2=1v=12av=kTm

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Most popular questions from this chapter

For a diatomic gas near room temperature, the internal partition function is simply the rotational partition function computed in section 6.2, multiplied by the degeneracy Zeof the electronic ground state.

(a) Show that the entropy in this case is

S=NkInVZeZrotNvQ+72.

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(b) Calculate the chemical potential of oxygen in earth's atmosphere near sea level, at room temperature. Express the answer in electron-volts

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where is the spacing between the two lowest levels. Thus, the levels get closer together with increasing energy. (This formula is reasonably accurate only up to about n = 15; for slightly higher n it would say that En decreases with increasing n. In fact, the molecule dissociates and there are no more discrete levels beyond n 15.) Use a computer to calculate the partition function, average energy, and heat capacity of a system with this set of energy levels. Include all levels through n = 15, but check to see how the results change when you include fewer levels Plot the heat capacity as a function of kT/. Compare to the case of a perfectly harmonic oscillator with evenly spaced levels, and also to the vibrational portion of the graph in Figure 1.13.

A water molecule can vibrate in various ways, but the easiest type of vibration to excite is the "flexing' mode in which the hydrogen atoms move toward and away from each other but the HO bonds do not stretch. The oscillations of this mode are approximately harmonic, with a frequency of 4.8 x 1013Hz. As for any quantum harmonic oscillator, the energy levels are 12hf,32hf,52hf, and so on. None of these levels are degenerate.

(a) state and in each of the first two excited states, assuming that it is in equilibrium with a reservoir (say the atmosphere) at 300 K. (Hint: Calculate 2 by adding up the first few Boltzmann factors, until the rest are negligible.) Calculate the probability of a water molecule being in its flexing ground

(b) Repeat the calculation for a water molecule in equilibrium with a reservoir at 700 K (perhaps in a steam turbine).

Imagine a particle that can be in only three states, with energies -0.05 eV, 0, and 0.05 eV. This particle is in equilibrium with a reservoir at 300 K.

(a) Calculate the partition function for this particle.

(b) Calculate the probability for this particle to be in each of the three states.

(c) Because the zero point for measuring energies is arbitrary, we could just as well say that the energies of the three states are 0, +0.05 eV, and +0.10 eV, respectively. Repeat parts (a) and (b) using these numbers. Explain what changes and what doesn't.

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