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Reacting with water in an acidic solution at 35°C, sucrose (C12H22O11) decomposes into glucose role="math" localid="1647401074171" (C6H12O6)and fructose (C6H12O6)*according to the law of uninhibited decay. An initial amount of 0.40 mole of sucrose decomposes to 0.36 mole in 30 minutes. How much sucrose will remain after 2 hours? How long will it take until 0.10 mole of sucrose remains?

Short Answer

Expert verified

The amount of sucrose remaining after 2 hours is 0.26M.

It will take 6.58 hours until 0.10 mole of sucrose remains.

Step by step solution

01

Step 1. Given information

Reacting with water in an acidic solution at 35°C, sucrose decomposes into glucose and fructose according to the law of uninhibited decay. An initial amount of 0.40 mole of sucrose decomposes to 0.36 mole in 30 minutes.

02

Step 2. Amount of sucrose remaining after 2 hours 

The amount of material present at a time t is given by the function At=A0ektwhere k<0 represents the decay rate.

Substitute localid="1647401702638" At=0.36,A0=0.40,t=0.5in the function At=A0ekt

At=A0ekt0.36=0.40ek×0.50.360.40=ek×0.5ln0.9=lnek×0.5ln0.9=k×0.5k=ln0.90.5k=-0.211

The amount of sucrose remaining after 2 hours can be calculated by substituting

role="math" localid="1647401837394" A0=0.40,t=2,k=-0.211in the function role="math" localid="1647401905449" At=A0ekt

At=A0ektAt=0.40e-0.211×2At=0.26

03

Step 3. 0.10 mole of sucrose remains 

Substitute A0=0.40,At=0.10,k=-0.211in the function At=A0ekt

At=A0ekt0.10=0.40e-0.211t0.100.40=e-0.211tln0.25=lne-0.211tln0.25=-0.211tt=ln0.25-0.211t=6.58hours

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