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The data from 200 endothermic reactions involving sodium bicarbonate are summarized as follows: $$ \begin{array}{cc} \text { Final Temperature } & \text { Number of } \\ \text { Conditions } & \text { Reactions } \\ \hline 266 \mathrm{~K} & 48 \\ 271 \mathrm{~K} & 60 \\ 274 \mathrm{~K} & 92 \end{array} $$ Calculate the probability mass function of final temperature.

Short Answer

Expert verified
The PMF is: P(266 K) = 0.24, P(271 K) = 0.30, P(274 K) = 0.46.

Step by step solution

01

Summarize Reaction Data

Begin by noting the number of reactions at each final temperature. We have: 48 reactions at 266 K, 60 reactions at 271 K, and 92 reactions at 274 K, making the total number of reactions 200.
02

Calculate Total Reactions

The total number of reactions is the sum of reactions at all temperatures: \[ 48 + 60 + 92 = 200 \]
03

Determine Probability of Each Condition

The probability of each final temperature is determined by dividing the number of reactions for each temperature by the total number of reactions. For 266 K: \[ P(266) = \frac{48}{200} = 0.24 \] For 271 K: \[ P(271) = \frac{60}{200} = 0.30 \] For 274 K: \[ P(274) = \frac{92}{200} = 0.46 \]
04

Verify the Probability Mass Function

Ensure that the probabilities calculated sum to 1. \[ 0.24 + 0.30 + 0.46 = 1.00 \] This confirms the calculations are correct.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding Endothermic Reactions
Endothermic reactions are chemical processes that absorb energy from their surroundings, typically in the form of heat. These reactions often lead to a decrease in temperature of the system as the energy is drawn in to drive the reaction forward.
In many endothermic reactions, like those involving sodium bicarbonate (baking soda), it's common to observe this cooling effect. When sodium bicarbonate undergoes decomposition or reacts with acids, it absorbs heat and cools the surrounding environment.
This process is important for various applications, such as in baking, where it helps dough rise, and in chemistry labs, where it demonstrates energy transformation principles. Understanding endothermic reactions is crucial for interpreters as it influences design and analysis when experimenting or creating reactions.
The Role of Sodium Bicarbonate
Sodium bicarbonate, widely known as baking soda, is a common compound with many uses, from cooking to cleaning. In chemistry, it frequently acts as a base, neutralizing acids and driving endothermic reactions.
Its chemical formula is \( NaHCO_3 \), and it's known for breaking down to release carbon dioxide gas. This reaction is not only useful for baking and producing foams but also serves educational purposes in demonstrating chemical reactions in labs.
When sodium bicarbonate undergoes decomposition, it absorbs energy, leading to a decrease in temperature – a hallmark of endothermic reactions. This cooling effect can be measured and analyzed through experiments, making sodium bicarbonate a perfect subject for studying temperature changes during chemical reactions.
Determining Final Temperature in Reactions
The final temperature of a chemical reaction provides insights into the reaction's characteristics, such as whether it is endothermic or exothermic. In endothermic reactions like those involving sodium bicarbonate, the final temperature is typically lower due to heat absorption.
In practical applications, measuring the final temperature allows chemists to quantify the energy absorbed and understand the reaction's efficiency. Observing the change in temperature helps predict the extent to which the reaction has progressed.
In experiments recorded in data sheets like the problem provided, keeping track of distinct temperature conditions allows for the calculation of statistical measurements, like the probability function, which offers a deeper understanding of reaction tendencies under various conditions.
Introduction to Probability Calculation
Probability calculation is a fundamental aspect of statistics, commonly used in scientific analysis to predict the likelihood of different outcomes or events. A probability mass function (PMF) is a function that gives the probability of a discrete random variable being exactly equal to some value.
In the context of the given exercise, calculating the probability involves noting how frequently each final temperature occurs during the reactions and dividing it by the total number of reactions.
  • For 266 K: Probability \( P(266) = 0.24 \)
  • For 271 K: Probability \( P(271) = 0.30 \)
  • For 274 K: Probability \( P(274) = 0.46 \)
By calculating the sum of these probabilities to confirm it equals 1, we verify it's a valid PMF, ensuring that all possible outcomes in the sample space of this specific exercise have been accounted for.

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