Chapter 5: Problem 84
Which one of the following is/arc the incorrect statements? (a) Boric acid is a protonic acid (b) Beryllium exhibits coordination number of six. (c) Chlorides of borh beryllium and aluminium have bridged chloride structures in solid phase. (d) \(\mathrm{B}_{2} \mathrm{H}_{6}, 2 \mathrm{~N} 1 \mathrm{l}_{3}\) is known as Inorganic Benzene.
Short Answer
Step by step solution
Analyze Statement (a)
Evaluate Statement (b)
Consider Statement (c)
Verify Statement (d)
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Boric Acid
- Boric acid accepts hydroxide, forming tetrahydroxyborate \( [\text{B(OH)}_4^-] \)
- Releases protons indirectly
- Used in antiseptics, insecticides, and buffering solutions due to its mild acidity
Coordination Number
- Its small atomic size limits the number of atoms that can surround it
- Presence of only four valence electrons to share with ligands
Bridged Chloride Structures
- Shared chloride ions between metal centers
- Stabilization of electron-deficient metals
- Formation of extended 3D networks
Beryllium Chemistry
- Exhibits behavior more similar to aluminum than its group counterparts
- Forms covalent rather than ionic bonds
- Demonstrates diagonal relationship with aluminum, exhibiting similar properties such as amphoteric hydroxides
- Beryllium compounds, such as beryllides, exhibit high melting points and excellent thermal stability
Inorganic Benzene
- Isoelectronic with benzene, meaning it has the same number of electrons
- Alternating boron and nitrogen atoms within a hexagonal ring
- Both compounds display aromatic characteristics, such as delocalized electrons