Chapter 4: Problem 37
Porassium is produccd by clecrolyzing fused \(\mathrm{KCl}\) in a cell similar to one uscd for Na hur rhe cell must be opcratcd ar a higher rempcrarurc becausc: (a) \(\mathrm{KCl}\) has a higher melting point than NaCl. (b) \(\mathrm{K}\) is a stronger reducing agent than \(\mathrm{Na}\). (c) \(\mathrm{K}\) is morc clecropositive than \(\mathrm{Na}\). (d) \(\mathrm{K}\) has higher molring point than Na.
Short Answer
Step by step solution
Understanding the Question
Analyzing Option (a)
Analyzing Option (b)
Analyzing Option (c)
Analyzing Option (d)
Conclusion
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Melting Point
For compounds like potassium chloride \((\mathrm{KCl})\), having a higher melting point means more heat is required to transition from solid to liquid. This is significant in industrial processes such as electrolysis, where the substance must be in a liquid state to conduct electricity effectively.
Factors that influence melting points include:
- The strength of the forces between particles: Stronger forces mean a higher melting point.
- The arrangement of particles in the lattice structure: More complex arrangements can lead to higher melting points.
- The type of bonding within the compound: Ionic bonds tend to result in higher melting points compared to covalent bonds.
Potassium Chloride
Potassium chloride is known for:
- Its high melting point: \((\mathrm{KCl})\)'s melting point is approximately 770°C (1420°F), which is higher than sodium chloride \((\mathrm{NaCl})\).
- Its solubility in water: Dissolving \((\mathrm{KCl})\) in water releases potassium and chloride ions, which can conduct electricity.
- Its use in agriculture: It is often used as a fertilizer due to its potassium content, an essential nutrient for plant growth.
Electropositive Elements
Key aspects of electropositive elements include:
- Metallic Character: Generally, metals are electropositive and are found on the left side of the periodic table.
- Reactivity: Highly electropositive elements like potassium (\(mathrm{K}\)) react vigorously with non-metals like chlorine \((\mathrm{Cl}\)) to form ionic compounds.
- Electronegativity: Electropositive elements have low electronegativity, meaning they do not strongly attract electrons.