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A 2.000-g mixture containing only K2CO3(FM 138.21) and KHCO3(FM 100.12) requiredof 15.00 mL of 1.000MHCIfor complete titration. Find the mass of each component of the mixture.

Short Answer

Expert verified

The burden ofK2CO3 is present in the given mixture 1.811 g.

The burden ofKHCO3 in given mixture is 0.189 g.

Step by step solution

01

Definition of Molarity

  • The amount of a material in a given volume of solution is measured in molarity (M).
  • The mole of a solute per litre of a solution is known as molarity.
  • The molar concentration of a solution is also known as molarity.
02

Determine the mass of each component of the mixture

It is necessary to compute the mass of each species in a given mixture.

The ratio of moles of solute (in grammes) to the volume of the solution is known as molarity (in litres). The formula for calculating a solution's molarity is:

The mass of each species in a given mixture is to be calculated.

Given,

1.000MHCI

The reaction that takes place in a solid mixture is

K2CO3+2HCI→2KCIaq+H2O+CO2KHCO3+HCI→KCIaq+KCIaq+H2O+CO2

The number of moles in the

HCI=0.015L×1.000M=0.015molHCI

The vast majority of K2CO3andKHCO3

The mass of a given combination is K2CO3+ mass of KHCO3=2.000g

2molofK2CO3+molofKHCO3=0.015mol

It obtain by substituting y in the previous equation.

x=1.811gandy=0.189g

Each species' weight in a specific mixture was calculated.

The burden of K2CO3is present in the given mixture 1.811 g .

The burden of KHCO3in given mixture is 0.189 g.

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Ascorbic acid (vitamin C) reacts with according to the equation

Starch is used as an indicator in the reaction. The end point is marked by the appearance of a deep blue starch-iodine complex when the first fraction of a drop of unreacted I3-remains in the solution.

(a) Verify that the structures above have the chemical formulas written beneath them. You must be able to locate every atom in the formula. Use atomic masses from the periodic table on the inside cover of this book to find the formula mass of ascorbic acid.

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Ascorbic acid (vitamin C) reacts with I3-according to the equation

Starch is used as an indicator in the reaction. The end point is marked by the appearance of a deep blue starch-iodine complex when the first fraction of a drop of unreacted I3-remains in the solution.

(a) Verify that the structures above have the chemical formulas written beneath them. You must be able to locate every atom in the formula. Use atomic masses from the periodic table on the inside cover of this book to find the formula mass of ascorbic acid.

(b) If 29.41 mL of I3- solution are required to react with 0.197 0 g of pure ascorbic acid, what is the molarity of the I3- solution?

(c) A vitamin C tablet containing ascorbic acid plus inert binder was ground to a powder, and 0.424 2 g was titrated by 31.63 mL of I3-. Find the weight percent of ascorbic acid in the tablet.

Derive an expression analogous to Equation 7-12 for the titration of M+(concentration, CM0,volume=VM0) with X-(titrant concentration=cx0). Your equation should allow you to compute the volume of titrant (vx)as a function of[x-].

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