/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Q26P The retention volume of a solute... [FREE SOLUTION] | 91影视

91影视

Log out

Learning Materials

Features

Discover

Chapter 23: Q26P (page 630)

The retention volume of a solute is 76.2mL for a column withVm=16.6mL andVs=12.7mL . Calculate the retention factor and the partition coefficient for this solute.

Short Answer

Expert verified
  1. Retention factor = k = 3.59
  2. Partition coefficient= K = 4.69

Step by step solution

01

Given Information:

Vr=76.2mL,Vm=16.6mL,Vs=12.7mL

02

To find the Retention factor:

Retention factor as

k=Vr-VmVm

Substitute the given data values are

k=76.2mL-16.6mLVmk=3.59

03

To find the Partition coefficient;

K=k脳VmVs

Substitute the given data values are

k=3.59脳16.6mLK=4.69

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91影视!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Consider the extraction of 100mLofM+2by2mLof1脳10-5MdithizoneinCHCl3for which KL=1.1脳104,KM=7脳1024,Ka=3脳10-5,尾=5脳1018,n=2(a) Derive an expression for the fraction of metal ion extracted into the organic phase, in terms of the distribution coefficient and volumes of the two phases. (b) Prepare a graph of the percentage of metal ion extracted over the pH range 0 to 5.

The solute in Problem 23 - 8 is initially dissolved in 80.0 mL of water. It is then extracted six times with 10.0mL portions of chloroform. Find the fraction of solute remaining in the aqueous phase.

(a) Explain why the diffusion coefficient of CH3OHis greater than that of

sucrose in Table 23-1.

(b) Make an order-of-magnitude estimate of the diffusion coefficient of water

vapor in air at 298K.

Match statements 1鈥�5 with the band broadening terms in the second list.

1. Depends on radius of open tubular column.

2. Not present in an open tubular column.

3. Depends on length and radius of connecting tubing.

4. Increases with diffusion coefficient of solute.

5. Increases with thickness of stationary phase film.

A Multiple paths

B Longitudinal diffusion

Cm Equilibration time in mobile phase

Cs Equilibration time in stationary phase

EC Extra column band broadening

A Gas chromatogram of a mixture of toluene and ethyl acetate is shown here:

(a)Use the width of each peak (measured at the base)to calculate the number of theoretical plates in the column. Estimate all lengths to the nearest 0.1 mm.

(b)Using the width of the toluene peak at its base, calculate the width expected at half height. Compare the measured and calculated values. When the thickness of the the line is significant relative to the length being measured, it is important to take the pen line width into account. You can measure from the edge of one line to the corresponding edge of the other line,as shown here.
See all solutions

Recommended explanations on Chemistry Textbooks

Chemistry Branches

Read Explanation

The Earths Atmosphere

Read Explanation

Chemical Analysis

Read Explanation

Organic Chemistry

Read Explanation

Making Measurements

Read Explanation

Chemical Reactions

Read Explanation
View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.