/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Q11P To find the Ce4+ content of a so... [FREE SOLUTION] | 91Ó°ÊÓ

91Ó°ÊÓ

To find the Ce4+ content of a solid, 4.37 g were dissolved and treated with excess iodate to precipitate Ce(IO3)4. The precipitate was collected, washed well, dried, and ignited to produce 0.104 g of CeO2 (FM 172.114). What was the weight percent of Ce in the original solid?

Short Answer

Expert verified

The weight percent of Ce in the original solid is 1.94%.

Step by step solution

01

Calculate the moles of CeO2:

In this task we have 4.37 g of Ce4+dissolved and treated with the excess iodate to precipitate Ce(IO3)4. When the precipitate was ignited, it produced 0.104vg of CeO2 (FM 172.114). we will calculate the weight percent of Ce in the original solid.

Calculate the moles of CeO2:

n(CeO2)=m(CeO2)M(CeO2)n(CeO2)=0.104g172.114g/moln(CeO2)=6.043×10-4mol

Consider that n(CeO2)=n(Ce)so the previous value is also the number of moles of Ce.

02

Calculate the mass and the weight of Ce:

Mass of Ce:

m(Ce)=n×Mm(Ce)=(6.043×10-4mol)×(140.116g/mol)m(Ce)=0.08467g

weight percent of Ce in the original solid:

wt%=0.08567g4.37gwt%=0.0194=1.94%

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

A solid mixture weighing 0.5485 gcontained only ferrous ammonium sulfate hexahydrate and ferrous chloride hexahydrate. The sample was dissolved in 1MH2SO4 , oxidized to Fe3+ with H2O2, and precipitated with cupferron. The ferric cupferron complex was ignited to produce 0.1678 gof ferric oxide, Fe2O3(FM 159.69). Calculate the weight percent of Clin the original sample.

Propagation of error. A mixture containing only silver nitrate and mercurous nitrate was dissolved in water and treated with excess sodium cobalticyanide, Na3[Co(CN)6] to precipitate both cobalticyanide salts:

AgNO3FM169.873Ag3[Co(CN)6]FM538.643Hg2(NO3)2FM525.19(Hg2)3[Co(CN)6]2FM1633.62

(a) The unknown weighed 0.4321g and the product weighed 0.4515g. Find wt%AgNO3 in the unknown. Caution: Keep all the digits in your calculator or else serious rounding errors may occur. Do not round off until the end.

(b) Even a skilled analyst is not likely to have less than a 0.3% error in isolating the precipitate. Suppose that thege is negligible error in all quantities, except the mass of product, which has an uncertainty of0.30%. Calculate the relative uncertainty in the mass ofAgNO3 in the unknown.

Why is high relative supersaturation undesirable in a gravimetric precipitation?

Marie Curie dissolved 0.091 92 g of RaCl2 and treated it with excess AgNO3to precipitate 0.088 90 g of AgCl. In her time (1900), the atomic mass of Ag was known to be 107.8 and that of Cl

was 35.4. From these values, find the atomic mass of Ra that Marie Curie would have calculated.

1.475-g sample containing NH4Cl(FM53.491),K2CO3(FM 138.21), and inert ingredients was dissolved to give 0.100 L of solution. A 25.0-mL aliquot was acidified and treated with excess sodium tetraphenylborate,Na+B(C6H5)4-, to precipitateK+and

NH4+ions completely:

(C6H5)4B-+K+→(C6H5)4BK(s)FM358.33(C6H5)4B-+NH4+→(C6H5)4BNH4(s)FM337.27

The resulting precipitate amounted to 0.617 g. A fresh 50.0-mL aliquot of the original solution was made alkaline and heated to drive off all theNH3.

NH4++OH-→NH3(g)+H2O

It was then acidified and treated with sodium tetraphenylborate to give 0.554 g of precipitate. Find the weight percent ofNH4ClandK2CO3in the original solid.

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.