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Mn was used as an internal standard for measuring Fe by atomic absorption. A standard mixture containing 2.00μ²µ²Ñ²Ô/mLand2.50μ²µ¹ó±ð/mLgave a quotient (Fe signal/Mn signal) = 1.05 / 1.00. A mixture with a volume of 6.00 mLwas prepared by mixing 5.00 mLof unknown Fe solution with 1.00mLcontaining13.5μ²µ²Ñ²Ô/mL. The absorbance of this mixture at the Mn wavelength was 0.128, and the absorbance at the Fe wavelength was 0.185. Find the molarity of the unknown Fe solution.

Short Answer

Expert verified

The molarity of a Fe solution with an unknown molarity is8.33×10-5M

Step by step solution

01

Definition of molarity

  • The moles of a solute per litre of a solution are known as molarity.
  • The molar concentration of a solution is also known as molarity.
02

Determine the molarity of the unknown Fe solution.

8.33×10-5M.As illustrated below, the concentration of Mn in the supplied unknown combination is estimated,

(13.5μ²µ/mL)1.006.00=2.25μ²µ/mL

For a standard combination, combine:

role="math" localid="1663655475613" AxX=FAsS1.052.50μ²µ/mL=F1.002.00μ²µ/mLF=1.052.50μ²µ/mL×2.00μ²µ/mL1.00=2.1μ²µ/mL2.50μ²µ/mL=0.840

In the case of an unknown mixture:

AxX=FAsS0.185Fe=0.8400.1282.25μ²µ/mL0.185Fe=0.107522.25μ²µ/mLFe=0.185×2.25μ²µ/mL0.10752=0.41625μ²µ/mL0.10752=3.87μ²µ/mL

The Fe concentration at the beginning has to be,

6.00/5.00(3.87μg/mL)=4.65μg/mL

The molarity of this can be stated as

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