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Chapter 8: Q9 TY (page 171)

Write the mass balance for a saturated solution of $Ba {({HsO}_{4})}_{2}$ if the species in solution are $B a^{2 +}, b a S O_{4} (a q), H S O_{4}^{-}, S O_{4}^{2 -}$ and ${BaOH}^{+}$ .SO

Short Answer

Expert verified

The mass balance equation for the ${BaOH}^{+}$ solution is

$2 \{[{Ba}^{2 +}] + [{BaSO}_{4 (aq)}] + [{BaOH}^{+}]\} = [{SO}_{4}^{2 -}] + [{HSO}_{4}^{-}] + [{BaSO}_{4} (nq)]$ .

Step by step solution

01

Concept used.

Mass balance:

All species in a solution containing a certain atom (or group of atoms) must be equal to the amount of that atom (or group) given to the solution.

02

Step 2: Calculate the two mass balances.

Species in solution: ${Ba}^{2 +}, {baSO}_{4} (aq), {HSO}_{4}^{-}, {SO}_{4}^{2 -}$ and ${BaOH}^{+}$ .

By definition Of mass balancerole="math" localid="1663415504126" $Ba {(H S O_{4})}_{2}$ solution is

$2 脳 total barium = total sulfate$

The mass balance equation is

$2 \{[{Ba}^{2 +}] + [{BaSO}_{4 (aq)}] + [{BaOH}^{+}]\} = [{SO}_{4}^{2 -}] + [{HSO}_{4}^{-}] + [{BaSO}_{4} (nq)]$

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Most popular questions from this chapter

The equilibrium constant for dissolution of a non ionic compound, such as diethyl ether $({CH}_{3} {CH}_{2} {OCH}_{2} {CH}_{3})$ , in water can be written

$ether (I) 謴 ether (aq) K = [ether (aq)] 纬_{ether}$

At low ionic strength, role="math" localid="1654837696819" $纬鈮� 1$ for neutral compounds. At high ionic strength, most neutral molecules can be salted out of aqueous solution. That is, when a high concentration typically $(> 1 M)$ of a salt such as $NaCI$ is added to aqueous solution, neutral molecules usually becomes less soluble. Does the activity coefficient, $纬_{ether}$ increases or decreases at high ionic strength?

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your answer as much as possible.

Including activity coefficient, find $[{Hg}_{2}^{2 +}]$ in saturated ${Hg}_{2} {Br}_{2}$ in localid="1654854633986" $0.001 00 M KBr$ .

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Color Plate 4 shows how the color of the acid-base indicatorbromocresol green (H2BG) changes as NaCl is added to an aqueoussolution of (H1)(HBG2). Explain why the color changes from palegreen to pale blue as NaCl is added.

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