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A procedure to measure the alkalinity (Box 11-1) of home swimming pool water is to titrate a fixed volume of pool water by counting the number of drops of the standard H2SO4to reach the bromocresol green endpoint. Explain what is measured in this titration and why bromocresol green was chosen.

Short Answer

Expert verified

The concentration of hydroxide, carbonate, bicarbonate ions and other ions present in the pool water is measured with the help of an indicator named Bromocresol green.

Here, Bromocresol green is chosen because while titrating with standard acid the pool water reacts with protons in acid and reaches a pH of 4.5. The endpoint is observed as green in color.

Step by step solution

01

The equivalence point and indicator.

The equivalence point ensures the titration reaction becomes completed and at this point, the number of moles of titrant and the number of moles of analyte remains equal.

A chemical compound called anindicator indicates the end of the reaction by color change. The endpoint refers to the color change and indicates the equivalence point has been reached.

02

 A procedure to measure the alkalinity

  • One of the techniques to determine the alkalinity in pool water is titrating it with standardized acid.

  • The reason for the alkaline nature of pool water is the presence of ions like hydroxide, carbonate, bicarbonate, etc. Here, the pH ofpool water remains above 7 (basic).

  • The concentration of hydroxide, carbonate, bicarbonate ions and other ions present in the pool water is measured with the help of an indicator namedBromocresol green.

  • The solution in presence of this indicator becomesblue in color above the pHvalue of5.4and becomesyellow in color at pH below 3.8.

While titrating with standard acid the pool water reacts with protons in acid and reaches a pH of 4.5 which is intermediate between 3.8 and 5.4. Thus, the endpoint is observed asgreen in color which isintermediate to that of yellow and blue.

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Most popular questions from this chapter

Consider the titration of weak acid HAwith NaOH. At what fraction of Vedoes ? At what fraction Veof does localid="1655007666473" pH=pKa-1ml? Use these two points, plus Vb=0,12Ve,Ve,1.2Veto sketch the titration curve for the reaction of 100Mof localid="1655007634810" 0.100Manilinium bromide (aminobenzene. ) withlocalid="1655007889912" 0.100MNaOH.

Titration on Diprotic Systems

11-30. This problem deals with the amino acid cysteine, which we will abbreviate H2C.

(a) A 0.0300Msolution was prepared by dissolving dipotassium cysteine, in water. Then of this solution were titrated with 0.0600MHCIO4. Calculate the pHat the first equivalence point.

(b) Calculate the quotient [C2-]/[HC-] in a solution of cysteinium bromide (the saltH3C+Br-).

The dibasic compound B (pKb1 = 4.00, pKb2 = 8.00) was titrated with 1.00 M HCl. The initial solution of B was 0.100 M and had a volume of 100.0 mL. Find the pH at the following volumes of acid added and make a graph of pH versus Va: Va = 0, 1, 5, 9, 10, 11, 15, 19, 20, and 22 mL

Why does an acid-base titration curve (pH versus volume of titrant) have an abrupt change at the equivalence point?

11-22. The figure compares the titration of a monoprotic weak acid with a monoprotic weak base and the titration of a diprotic acid with a strong base.

(a) Write the reaction between the weak acid and the weak base and show that the equilibrium constant is 107.78. This large value means that the reaction goes "to completion" after each addition of the reagent.

(b) Why doespK2intersect the upper curve at 32Ve and the lower curve at 2Ve? On the lower curve, "pK2"is pKathe acid, BH+.


(a) Titration of 100mL of 0.050MH2A(pK1=2.86,pK2=10.64) with 0.050 M NaOH.

(b) Titration of 100mL of the weak acid localid="1663575238403" HA(0.050M,pKa=2.86) with the weak baselocalid="1663575247899" B(0.050M,pKb=3.36).

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