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Find the equilibrium constant for the reaction: \(\mathrm{A}(\mathrm{g})+\mathrm{B}(\mathrm{g}) \rightleftharpoons 2 \mathrm{C}(\mathrm{g})\) at \(25^{\circ} \mathrm{C}\) when \(\mathrm{k}\) equals \(1.4 \times 10^{-12} \mathrm{M}^{-1} \mathrm{~s}^{-1}\) for the reaction \(\mathrm{A}(\mathrm{g})+\mathrm{B}(\mathrm{g}) \rightarrow\) \(2 \mathrm{C}\) (g) at \(25^{\circ} \mathrm{C}\) and \(\mathrm{k}\) equals \(2.7 \times 10^{-13} \mathrm{M}^{-1} \mathrm{~s}^{-1}\) for the reaction: \(2 \mathrm{C}(\mathrm{g}) \rightarrow \mathrm{A}(\mathrm{g})+\mathrm{B}(\mathrm{g})\) at \(25^{\circ} \mathrm{C}\) a. \(5.2\) b. \(6.4\) c. \(3.6\) d. \(7.1\)

Short Answer

Expert verified
The equilibrium constant is approximately 5.2 (option a).

Step by step solution

01

Understand the Reaction Dynamics

We are dealing with the reaction \( \mathrm{A} + \mathrm{B} \rightleftharpoons 2 \mathrm{C} \), which involves a forward and a reverse reaction. The rate constants for these reactions are provided as \( k_f \) for the forward and \( k_r \) for the reverse.
02

Recognize Given Rate Constants

The forward reaction rate constant \( k_f \) is given as \( 1.4 \times 10^{-12} \mathrm{M}^{-1} \mathrm{s}^{-1} \) for \( \mathrm{A} + \mathrm{B} \rightarrow 2 \mathrm{C} \). The reverse reaction rate constant \( k_r \) is \( 2.7 \times 10^{-13} \mathrm{M}^{-1} \mathrm{s}^{-1} \) for \( 2 \mathrm{C} \rightarrow \mathrm{A} + \mathrm{B} \).
03

Apply Equilibrium Constant Formula

The equilibrium constant \( K \) for the reaction can be found using the relation \( K = \frac{k_f}{k_r} \). This formula comes from the fact that at equilibrium, the rate of the forward reaction equals the rate of the reverse reaction.
04

Calculate Equilibrium Constant

Substitute the given values into the formula: \[ K = \frac{1.4 \times 10^{-12}}{2.7 \times 10^{-13}} \]. Calculate this division to find \( K \).
05

Perform the Calculation

Divide the numbers: \[ K = \frac{1.4}{2.7} \times 10^{-12 + 13} = \frac{1.4}{2.7} \times 10^{1} \]. Simplify: \[ K = \frac{1.4}{2.7} \times 10 = 0.5185 \times 10 = 5.185 \].
06

Select the Closest Answer

Among the given options, \( 5.2 \) (option a) is the closest approximation to the calculated value \( 5.185 \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Reaction Dynamics
In the world of chemistry, understanding the reaction dynamics is key to diving deeper into how substances interact, transform, and reach a state of balance. The reaction in question is given by \( \mathrm{A} + \mathrm{B} \rightleftharpoons 2 \mathrm{C} \), characterizing what's known as a reversible reaction. Here, two individual reactants, \( \mathrm{A} \) and \( \mathrm{B} \), combine to form two molecules of a product, \( \mathrm{C} \), and vice versa. The arrow symbol \( \rightleftharpoons \) indicates that the reaction can proceed in both directions: forward, forming \( \mathrm{C} \), and reverse, decomposing \( \mathrm{C} \) back into \( \mathrm{A} \) and \( \mathrm{B} \).

These dynamics lay the foundation for the concepts of reaction rates and equilibrium, which are critical to understanding how chemical reactions occur and stabilize. To achieve equilibrium, the rates of the forward and reverse reactions must balance out, meaning the amount of products and reactants remain constant over time.
Rate Constant
The rate constant, crucial in the study of reaction kinetics, is symbolized as \( k \). It quantifies the speed of a reaction, indicating how quickly or slowly a reaction proceeds under given conditions.

For the forward reaction \( ( \mathrm{A} + \mathrm{B} \rightarrow 2 \mathrm{C} ) \), the rate constant is \( 1.4 \times 10^{-12} \mathrm{M}^{-1} \mathrm{s}^{-1} \), signifying the rate at which \( \mathrm{A} \) and \( \mathrm{B} \) transform into \( \mathrm{C} \). Conversely, for the reverse reaction \( (2 \mathrm{C} \rightarrow \mathrm{A} + \mathrm{B} ) \), the rate constant is \( 2.7 \times 10^{-13} \mathrm{M}^{-1} \mathrm{s}^{-1} \). These constants reflect how frequently and effectively the molecules collide to produce a successful reaction event.

Understanding these constants provides insight into the intrinsic nature of the reactions—whether they are inclined to proceed swiftly or at a more leisurely pace.
Forward Reaction
The forward reaction involves the conversion of reactants, \( \mathrm{A} \) and \( \mathrm{B} \), into the product, \( 2 \mathrm{C} \). This process is characterized by the rate constant \( k_f = 1.4 \times 10^{-12} \mathrm{M}^{-1} \mathrm{s}^{-1} \). This value tells us how efficiently the forward reaction progresses under the specific conditions, such as temperature.

A higher rate constant typically indicates a more rapid reaction. This means more molecules of \( \mathrm{A} \) and \( \mathrm{B} \) are swiftly converted into \( \mathrm{C} \), contributing to a shift towards the products and influencing the position of equilibrium.

The forward reaction is crucial for the establishment of a productive cycle in which the system can stabilize at equilibrium, given the right conditions.
Reverse Reaction
The reverse reaction represents the process by which the product, \( 2 \mathrm{C} \), decomposes back into the original reactants, \( \mathrm{A} \) and \( \mathrm{B} \). This backward march in reaction dynamics is governed by the rate constant \( k_r = 2.7 \times 10^{-13} \mathrm{M}^{-1} \mathrm{s}^{-1} \).

In this scenario, the rate constant explains how ready the molecules of \( \mathrm{C} \) are to revert to \( \mathrm{A} \) and \( \mathrm{B} \). With a lower rate constant compared to the forward reaction, it signifies slower progress, indicating fewer successful collisions occurring to break \( \mathrm{C} \) down into reactants. This plays a pivotal role in determining how quickly equilibrium can be reached and maintained.

Understanding the reverse reaction is critical, as it balances the equation and affects the equilibrium constant, providing insight into the stability and directionality of chemical processes.

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Most popular questions from this chapter

If \(\mathrm{Ag}^{+} \mathrm{NH}_{3} \rightleftharpoons\left[\mathrm{Ag}\left(\mathrm{NH}_{3}\right)\right]^{+} ; \mathrm{K}_{1}=3.5 \times 10^{-3}\) and \(\left[\mathrm{Ag}\left(\mathrm{NH}_{3}\right)\right]^{+}+\mathrm{NH}_{3} \rightleftharpoons\left[\mathrm{Ag}\left(\mathrm{NH}_{3}\right)_{2}\right]^{+} ; \mathrm{K}_{2}=1.74 \times 10^{-3}\) the formation constant of \(\left[\mathrm{Ag}\left(\mathrm{NH}_{3}\right)_{2}\right]^{+}\)is

\((\mathbf{A}):\) When \(0.1 \mathrm{M}\) diprotic weak acid \(\mathrm{H}, \mathrm{X}\) dissociates with its dissociation constants \(\mathrm{K}_{\mathrm{a}}=10^{-4}\) and \(\mathrm{K}_{\mathrm{a} 2}\) \(=10^{-12}\), then \(\left[\mathrm{X}^{-2}\right]\) is almost equal to \(10^{-12} \mathrm{M}\) \((\mathbf{R}):\) Since \(K_{a 2}<<\mathbb{K}_{a 1}\) for \(0.1 \mathrm{M}\) so \(\mathrm{H}_{2} \mathrm{X}\) so \(\left[\mathrm{X}^{-2}\right]\) is negligible w.r.t. \(\left[\mathrm{HX}^{-}\right]\). Hence \(\left[\dot{\mathrm{X}}^{-2}\right] \approx \mathrm{K}_{\mathrm{a} 2}\)

The equilibrium constant for the reaction \(\mathrm{CaCO}_{3}(\mathrm{~s}) \rightleftharpoons \mathrm{CaO}(\mathrm{s})+\mathrm{CO}_{2}(\mathrm{~g})\) can be given as a. \(\mathrm{K}_{\mathrm{C}}=\left([\mathrm{CaO}]\left[\mathrm{CO}_{2}\right]\right) /\left[\mathrm{CaCO}_{3}\right]\) b. \(\mathrm{K}_{\mathrm{c}}=\left[\mathrm{CO}_{2}\right]\) c. \(\mathrm{K}_{\mathrm{p}}=\mathrm{P}_{\mathrm{CO}_{2}}\) d. \(\mathrm{K}_{\mathrm{C}}=\left[\mathrm{CaCO}_{3}\right] /\left([\mathrm{CaO}]\left[\mathrm{CO}_{2}\right]\right)\)

For the gas phase reaction, \(\mathrm{C}_{2} \mathrm{H}_{4}+\mathrm{H}_{2} \rightleftharpoons \mathrm{C}_{2} \mathrm{H}_{6}(\Delta \mathrm{H}=-32.7 \mathrm{kcal})\), carried out in a closed vessel, the equilibrium concentration of \(\mathrm{C}_{2} \mathrm{H}_{4}\) can be increased by a. Decreasing the pressure b. Adding some \(\mathrm{C}_{2} \mathrm{H}_{6}\) c. Increasing the temperature d. Removing some \(\mathrm{H}\),

Which metal sulphides can be precipitated from a solution that is \(0.01 \mathrm{M}\) in \(\mathrm{Mn}^{2+}, \mathrm{Zn}^{2+}, \mathrm{Pb}^{2+}\) and \(\mathrm{Cu}^{2+}\) and \(0.10 \mathrm{M}\) in \(\mathrm{H}_{2} \mathrm{~S}\) at a \(\mathrm{pH}\) of \(1.0\) ? Metal sulphide \(\quad \mathrm{Ksp}\) MnS \(3 \times 10^{16}\) ZnS \(3 \times 10^{-2}\) PbS \(3 \times 10^{-7}\) \(\mathrm{CuS} \quad 6 \times 10^{-16}\) a. \(\mathrm{CuS}\) b. \(\mathrm{MnS}\) c. \(\mathrm{ZnS}, \mathrm{PbS}, \mathrm{CuS}\) d. PbS, CuS

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