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A gas sample is known to be a mixture of ethane and butane, A bulb having a \(230.0 \mathrm{cm}^{3}\) capacity is filled with the gas to a pressure of \(97.5 \times 10^{3}\) Pa at \(23.1^{\circ} \mathrm{C}\). If the mass of the gas in the bulb is \(0.3554 \mathrm{g}\). what is the mole percent of butane in the mixture?

Short Answer

Expert verified
The mole percent of butane in the gas mixture is approximately 4.03%.

Step by step solution

01

Convert the temperature to Kelvin and volume to m鲁

First, we need to convert the given temperature from degrees Celsius to Kelvin using the following equation: Kelvin Temperature = Celsius Temperature + 273.15 T = 23.1 + 273.15 = 296.25 K Next, we convert the given volume from cm鲁 to m鲁: 230.0 cm鲁 = 230.0 x 10鈦烩伓 m鲁
02

Calculate the total moles of gas in the bulb using the Ideal Gas Law equation

Now we will use the Ideal Gas Law equation, PV = nRT, to determine the total moles of gas in the bulb. We need to rearrange the equation to solve for n: n = PV / RT Substitute the given values and constants (R = 8.314 J/(mol路K)): n = (97.5 x 10鲁 Pa)(230.0 x 10鈦烩伓 m鲁) / (8.314 J/(mol路K))(296.25 K) n 鈮 0.0113 mol
03

Calculate the gas sample鈥檚 molar mass

To find the molar mass of the gas sample, divide its mass by the total moles of gas: Molar Mass = Mass / Moles Molar Mass = 0.3554 g / 0.0113 mol 鈮 31.44 g/mol
04

Find mole fractions of ethane and butane

Let x be the mole fraction of butane in the mixture. Then, the mole fraction of ethane in the mixture is (1 鈥 x). We can express the total molar mass of the gas sample as the weighted average of the molar masses of ethane and butane: Mixture Molar Mass = x路M_butane + (1 鈥 x)路M_ethane = 31.44 g/mol Given that the molar mass of butane (C鈧凥鈧佲個) is 58.12 g/mol and the molar mass of ethane (C鈧侶鈧) is 30.07 g/mol, plug these values into the equation: 31.44 = x路58.12 + (1 鈥 x)路30.07 Now, we will solve for the mole fraction of butane, x.
05

Solve for the mole fraction of butane

Rearrange the equation and solve for the mole fraction of butane (x): x = (31.44 - 30.07) / (58.12 - 30.07) 鈮 0.0403 x 鈮 4.03%
06

Calculate the mole percent of butane in the gas mixture

The mole fraction of butane in the gas mixture is approximately 4.03%. Therefore, the mole percent of butane in the mixture is: Mole Percent of Butane = 4.03%

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Mole Fraction
The mole fraction of a component in a gas mixture is a measure of its concentration in the mixture. It tells you how much of the mixture is made up of that particular gas. To calculate the mole fraction of a gas, you need the number of moles of the gas and the total number of moles of the mixture. The formula is: \[ \text{Mole Fraction} = \frac{\text{Moles of Component}}{\text{Total Moles of Mixture}} \]In the context of our exercise, the mole fraction of butane was determined using the molar masses as a weighted average. This step involved blending the individual contributions of ethane and butane to reach the overall molar mass of the gas sample. Understanding mole fractions is essential as it provides a basis for determining the composition of a gas mixture.
Pressure and Temperature Conversion
When dealing with gases, starting calculations using standard units is crucial for accuracy. Pressure and temperature often need to be converted from one unit to another. Temperature is usually provided in degrees Celsius but needs to be converted into Kelvin for the purpose of gas law calculations. The formula to convert Celsius to Kelvin is:\[ T_{\text{Kelvin}} = T_{\text{Celsius}} + 273.15 \]In our exercise, the temperature was converted from 23.1掳C to 296.25 K.Similarly, the volume given in cubic centimeters (cm鲁) needed conversion to cubic meters (m鲁) by multiplying with 10鈦烩伓 because the Ideal Gas Law requires standard SI units for its variables.Applying these conversions ensures that the equation is carried out in a cohesive set of units, aiding in accurate calculations of other variables.
Molar Mass Calculation
Molar mass is the mass of one mole of a substance and is crucial for converting between the mass of a substance and the amount of substance in moles. In the ideal gas context, to find the molar mass of a gas mixture, you divide the mass of the gas sample by the total number of moles, calculated using the Ideal Gas Law. The relation is:\[ \text{Molar Mass} = \frac{\text{Mass}\ ( ext{g})}{ ext{Moles}\ ( ext{mol})} \]In our gas sample problem, the molar mass was computed as 31.44 g/mol using a mass of 0.3554 g and 0.0113 mols of gas. This calculation links the mass of the gas to the number of moles, a crucial element in determining the composition of gas mixtures like ethane and butane.
Gas Mixtures
Gas mixtures consist of two or more different gases. Each component contributes to the overall pressure, volume, and amount in the mixture. In mixtures like the one involving ethane and butane, their individual properties influence the bulk properties of the mixture. The Ideal Gas Law, given as \( PV = nRT \), applies to the entire gas mixture instead of individual components, using the total number of moles and the overall measurements of pressure and volume.In our case, we calculated the contributions of ethane and butane to the mixture. By balancing these with their respective molar masses, we could compute the mole fraction of butane.For anyone working with or studying gas mixtures, knowing how to manipulate these calculations is essential for both practical applications and understanding theoretical concepts.

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Most popular questions from this chapter

Use the ideal gas and van der Waals equations to calculate the pressure when \(2.25 \mathrm{mol} \mathrm{H}_{2}\) are confined to a volume of \(1.65 \mathrm{L}\) at \(298 \mathrm{K}\). Is the gas in the repulsive or attractive region of the molecule-molecule potential?

An initial step in the biosynthesis of glucose \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\) is the carboxylation of pyruvic acid \(\mathrm{CH}_{3} \mathrm{COCOOH}\) to form oxaloacetic acid HOOCCOCH \(_{2} \mathrm{COOH}\) \\[ \mathrm{CH}_{3} \mathrm{COCOOH}(s)+\mathrm{CO}_{2}(g) \rightarrow \mathrm{HOOCCOCH}_{2} \mathrm{COOH}(s) \\] If you knew nothing else about the intervening reactions involved in glucose biosynthesis other than no further carboxylations occur, what volume of \(\mathrm{CO}_{2}\), is required to produce \(1.10 \mathrm{g}\) of glucose? Assume \(P=1\) atm and \(T=298 \mathrm{K}\).

Calculate the pressure exerted by benzene for a molar volume of \(2.00 \mathrm{L}\) at \(595 \mathrm{K}\) using the Redlich-Kwong equation of state: \\[ \begin{aligned} P &=\frac{R T}{V_{m}-b}-\frac{a}{\sqrt{T}} \frac{1}{V_{m}\left(V_{m}+b\right)} \\\ &=\frac{n R T}{V-n b}-\frac{n^{2} a}{\sqrt{T}} \frac{1}{V(V+n b)} \end{aligned} \\] The Redlich-Kwong parameters \(a\) and \(b\) for benzene are \(452.0 \mathrm{bar} \mathrm{dm}^{6} \mathrm{mol}^{-2} \mathrm{K}^{1 / 2}\) and \(0.08271 \mathrm{dm}^{3} \mathrm{mol}^{-1},\) respec- tively. Is the attractive or repulsive portion of the potential dominant under these conditions?

When Julius Caesar expired, his last exhalation had a volume of \(450 . \mathrm{cm}^{3}\) and contained 1.00 mole percent argon. Assume that \(T=300 . \mathrm{K}\) and \(P=1.00\) atm at the location of his demise. Assume further that \(T\) has the same value throughout Earth's atmosphere. If all of his exhaled Ar atoms are now uniformly distributed throughout the atmosphere, how many inhalations of \(450, \mathrm{cm}^{3}\) must we make to inhale one of the Ar atoms exhaled in Caesar's last breath? Assume the radius of Earth to be \(6.37 \times 10^{6} \mathrm{m}\). [Hint: Calculate the number of Ar atoms in the atmosphere in the simplified geometry of a plane of area equal to that of Earth's surface. See Problem P1.20 for the dependence of the barometric pressure and the composition of air on the height above Earth's surface.

Liquid \(\mathrm{N}_{2}\) has a density of \(875.4 \mathrm{kg} \mathrm{m}^{-3}\) at its normal boiling point. What volume does a balloon occupy at \(298 \mathrm{K}\) and a pressure of 1.00 atm if \(3.10 \times 10^{-3} \mathrm{L}\) of liquid \(\mathrm{N}_{2}\) is injected into it? Assume that there is no pressure difference between the inside and outside of the balloon.

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