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Chapter 1: 24P (page 82)

a. CHF=CHF

b. F2C=CHG2

c. CH2=CHCH2CH3

d.

e.

f.

Short Answer

Expert verified

Only compound (a) will show cis-trans isomerism.

Step by step solution

01

Cis-trans isomerism

Cis-trans isomerism is observed in alkenes and alicyclic compounds. For an alkene to show cis-trans isomerism, it must have two different substituents.Cis-trans isomers are geometric isomers that are the subset of stereoisomers.

02

Rules for displaying cis-trans isomerism

The compounds with the following substitution pattern would not show cis-trans isomerism.

Cis-trans isomerism would not be observed for alkenes with this substitution pattern.

03

Determination of compounds that show cis-trans isomerism

Compounds (b), (c), and (d) would not show cis-trans isomerism.

Cis-trans notation cannot be used for alkenes with more than two different substituents. Hence, the compound (e) and (f) would not show cis-trans isomerism. For these compounds E/Z notation system is appropriate.

The only compound that will exhibit cis-trans isomerism is compound (a). Cis-trans isomers of compound (a) are,

Cis-trans isomerism of compound (a).

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Most popular questions from this chapter

For each of the following structures,

1. Draw a Lewis structure; fill in any non bonding electrons.

2. Calculate the formal charge on each atom other than hydrogen.

Name the element that corresponds to each electronic configuration.

  1. 1s22s22p63s1
  2. 1s22s22p6
  3. 1s22s22p1
  4. 1s22s22p63s2

In the following sets of resonance forms, label the major and minor contributors and state which structures would be of equal energy. Add any missing resonance forms.

Draw Lewis structures for

  1. Two compounds of formula C4H10
  2. Two compounds of formula C2H6O
  3. Two compounds of formula C2H7N
  4. Three compounds of formulaC2H7NO
  5. Three compounds of formulaC3H8O2
  6. Three compounds of formulaC2H4O

For each of these ions, draw the important resonance forms and predict which resonance form is likely to be the major contributor.
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